Chapter 5

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Atomic radii

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45 Terms

1

Atomic radii

1/2 the distance between the nuclei of identical atoms that are bonded together

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2

Period- atoms get smaller b/c of increasing + charge of the nucleus

Group- atoms get larger b/c of increase of energy levels as you go down

What happens to the period trend and group trend for atomic radii?

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3

Ionization energy

The energy required to remove one electron from a neutral atom of an element

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4

Period- increase b/c of increasing nuclear charge, higher charge more strongly attracts e- in same energy level

Group- decreased b/c increase of energy levels, the e- are further from the nucleus and therefor easier to remove

What happens to the period trend and group trend for ionization energy?

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5

Electron affinity

The energy change that across when an electron is gained by a neutral atom

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6

Period- increase b/c number becomes more - b/c energy gives off a negative value

Group- decreases b/c e- are added with greater difficulty due to 1. slight increase in nuclear charge 2. Increase in atomic radii

What happens to the period trend and group trend for electron affinity?

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7

Electronegativity

A measure of the ability of an atom in a chemical compound to allow e- from another atom in the compound

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8

Period- increase b/c more + nucleus

Group- decrease b/c shielding effect

What happens to the period trend and group trend for electronegativity?

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9

Ionic radii

Size of ions

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10

Period- cations (metals on left) & anions (nonmetals on right) decrease b/c of + nucleus

Group- increase due to adding energy

What happens to the period trend and group trend for ionic radii?

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11

An atom gets larger as the number of electronic shells increase

Why do atoms get larger as you move down a group/family but smaller as you go across a period?

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12

Ion

An atom or group of bonded atoms that has a + or - charge

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13

Cation

Positive ion (lose e-)

Decrease in size because more p+ so pull closer together

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14

Anion

Negative ion (gain e-)

Increase in size because more e- so don’t pull as close together; e- repel each other so they spread out

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15

Valence electrons

The e- in the outer most energy level available to be lost, gained, or shared in the formation

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16

Fluorine

What is the most electronegative element and given a value of 4.0

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17

True

When atoms become ions, their radii change t/f

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18

Ionization

Any process that results in the formation of an ion

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19

Outermost s&p sublevels

For main group elements’ valence e-, where are they located?

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20

Held tightly to nucleus

Why aren’t the inner e- involved in the valence shell?

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21

False (outer)

Only inner shell e- are involved in forming compounds

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22

E- are lost, gained or shared

How are chemical compounds formed?

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23

Cannizzaro

…… is credited with developing a method that led to the determination of relative atomic mass

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24

Mendeleev; atomic mass

… organized elements on the periodic table according to their increasing …

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25

atomic number; Moseley

The modern periodic table is now arranged in order of increasing ….. …… This was established by …..

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26

modern periodic law; atomic number

The ….. ….. …. states that the physical and chemical properties of the elements are periodic functions of their ……. …..

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27

alkali metals

alkaline earth metals

What groups are in s-block?

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28

halogens

metalloids

noble gases

other nonmetals

other metals

What groups are in p-block?

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29

transition metals

What groups are in d-block?

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30

lanthanides

actinides

What groups are in f-block?

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31

alkali metals

alkaline earth metals

What groups are too reactive to be found as a free element in nature?

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32

lanthanides

What group elements are shiny metals and similar to the reactivity of group 2 elements?

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33

largely unreactive

What is the most distinctive property of the noble gases is that they are…..

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34

group

The discovery of the noble gases changed Mendeleev’s periodic table by adding a new….

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35

modern periodic law

the physical and chemical properties of an element are functions of its atomic number

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36

alkali metals

silvery appearance

soft enough to cut with knife

very reactive, must be stored in kerosene b/c they will react the water in the air

not found in nature as free elements, only in compounds

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37

alkaline- earth metals

harder, denser, & stronger than alkali metals

higher boiling point

less reactive but also not found in nature as a free element

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38

H & He

unique, does not share the same properties of Group 1

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39

transition metals

metals w/ typical metallic properties

good conductors, high luster

typically less reactive than alkali and alkaline-earth metals

some so nonreactive they do not easily form a compounds & exist as free elements (gold, platinum, palladium are the least reactive)

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40

halogens

most reactive nonmetals

react very vigorously with most metals form salts

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41

metalloids

semiconducting elements

located in p-block with metals and nonmetals

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42

metals of the p-block

harder & denser than the s-block metals, but softer than the d-block metals

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43

lanthanides

shiny and similar to group 2 reactively

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44

actinides

radioactive and only 1st four found naturally on earth, the rest made in the lab

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45

main group elements

the p-block elements along w/ s-block elements

rt. hand side = metals

lt. side & bottom = nonmetals

middle = 6 metalloids (B, Si, Ge, As, Sb, Te)

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