Chemistry Chapter 5

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Electromagnetic radiation

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52 Terms

1

Electromagnetic radiation

a form of energy that exhibits wavelike behavior as it travels through space

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2

Wavelength

the shortest distance between 2 equivalent points on a continuous wave

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3

Units for wavelength

meter or nanometer

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4

Symbol for wavelength

lambda, λ

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5

Frequency

the number of waves that pass a given point per second

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6

Unit for frequency

hertz, 1/s

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7

Symbol for frequency

nu, ν

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8

Amplitude

the wave's height from the origin to a crest or trough

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9

Speed of light equation

c (speed of light, m/s) = λ (wavelength, m or nm) * ν (frequency, hertz)

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10

inversely

Wavelength and frequency vary ________.

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11

Electromagnetic spectrum

a spectrum that includes all forms of electromagnetic radiation

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12

Quantum theory

a theory created by Max Planck to explain how matter lost and gained only small, specific amounts of energy

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13

Quantum

the minimum amount of energy that can be lost or gained or gained by an atom

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14

Photon

a particle-like bundle of energy without mass that carries a quantum of electromagnetic energy

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15

Energy of a photon equation

E (energy, joules) = h (Planck's constant, joules * seconds) * ν (frequency, hertz)

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16

Spectroscopy

the method of studying substances exposed to energy

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17

Spectrum

the pattern of energy studied in spectroscopy

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18

Atomic emission spectrum

the set of frequencies or wavelengths of the electromagnetic waves emitted by atoms of the element

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19

unique

Each element produces a ________ line spectrum.

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20

Bohr's (planetary) model

an early atomic model of the hydrogen atom that was developed by studying the emission spectrum of hydrogen

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21

Accurate part of Bohr's model

the electron can only posses certain quantities of energy/ have certain allowed energy states

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22

Ground state

the lowest and most stable energy state

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23

Excited state

any state of energy that is more than the lowest amount

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24

Inaccurate part of Bohr's model

the electron moves around the nucleus in certain allowed circular orbits

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25

waves

Electrons should be thought of as ________ spread out in space. (Louis de Broglie)

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26

measurement

The act of ________ disturbs the object being measured.

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27

Heisenberg uncertainty principle

states that it is fundamentally impossible to know precisely both the velocity and position of a particle at the same time

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28

Quantum mechanical model

modern atomic model, a mathematical equation that treated an electron as a wave and solved the equation for the hydrogen atom

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29

Lowest energy level

1

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30

farther

The ________ the electron, the higher the energy level

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31

Energy sublevel

a subdivision of an energy level, assigned a letter: s, p, d, or f

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32

Atomic orbital

the volume around the nucleus in which the electron is likely to be found

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33

Sublevel "s"

spherical, 1 orientation

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34

Sublevel "p"

dumbbell, 3 orientations

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35

Sublevel "d"

cloverleaf, 4 orientations, dumbbell with donut, 1 orientation (5 orientations in total)

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36

Sublevel "f"

7 different orientations

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37

larger

The orbitals in the higher energy levels are ________ than the orbitals in the lower energy levels

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38

Max electrons in "s"

2

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39

Max electrons in "p"

6

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40

Max electrons in "d"

10

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41

Max electrons in "f"

14

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42

Electron configuration

a notation for showing how electrons are arranged in energy sublevels

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43

2

How many electrons can be in a sublevel

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44

Aufbau principle

sublevels are "filled" with electrons starting with the lowest energy sublevel

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45

Quantum numbers

a set of four numbers used to describe the properties in electrons in an atom

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46

Pauli exclusion principle

states that each electron in an atom has a unique set of 4 quantum numbers and that 2 electrons can be in an orbital only if they have opposite spins

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47

Abbreviated electron configuration

noble gas in brackets and portion of configuration that remains

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48

Orbital diagram

notation used to depict electrons in orbitals

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49

Hund's rule

the most stable arrangement of electrons within a sublevel is one with greatest number of parallel spins

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50

Degenerate

electrons with the same amount of energy

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51

Electron dot diagram/ Lewis dot structure

notation used tp symbolize atom's valence electrons

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52

Valence electron

the electrons in the outermost (largest) orbitals, determine element's properties

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