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Covalent Bond

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33 Terms

1

Covalent Bond

a bond formed by the sharing of electrons between atoms.

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2

Molecule

a neutral group of atoms joined together by covalent bonds.

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3

Diatomic molecule

a molecule consisting of two atoms.

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4

Molecular compound

a compound that is composed of molecules.

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5

Molecular formula

a chemical formula of a molecular compound that shows the kinds/numbers of atoms present in a molecule of a compound.

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6

Single covalent bond

a bond formed when two atoms share a pair of electrons

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7

Structural formula

a chemical formula that shows the arrangement of atoms in a molecule or a polyatomic ion; each dash between a pair of atoms indicates a pair of shared e-.

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8

Unshared pair

a pair of valence e- that is not shared between atoms.

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9

Double covalent bond

a bond in which two atoms share two pairs of e-

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10

Triple covalent bond

a covalent bond in which 3 pairs of e- are shared by two atoms

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11

Coordinate covalent bond

a covalent bond in which one atom contributes both bonding e-.

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12

Bond dissociation energy

the energy required to break the bond between 2 covalently bonded atoms; expressed in kJ per mol of substance.

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13

Resonance structure

one of the two or more equally valid e- dot structures of a molecule or polyatomic ion.

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14

Molecular orbital

: an orbital that applies to the entire molecule.

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15

Polyatomic ion:

a tightly bound group of atoms that behaves as a unit & has a positive or negative charge.

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16

Bonding orbital

a molecular orbital that can be occupied by 2 e- of a covalent bond

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17

Sigma bond

a bond formed when 2 atomic orbitals combine to form a molecular orbital that is symmetrical around the axis connecting the 2 atomic nuclei

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18

Pi bond

a covalent bond in which the bonding e- are most likely to be found in sausage shaped regions above & below the bond axis of the bonded atoms.

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19

Tetrahedral Angle

a bond angle of 109.5 that results when a central atom forms 4 bonds directed toward the center of a regular tetrahedron.

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20

VSEPR theory

valence-shell electron-pair repulsion theory; because e- pairs repel, molecules adjust their shapes so that valence e- pairs are as far apart as possible.

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21

Hybridization

the mixing of several atomic orbitals to form the same total number of equivalent hybrid orbitals.

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22

nonpolar covalent bond

: a covalent bond in which the e- are shared equally by the 2 atoms

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23

Polar covalent bond

: a covalent bond between atoms in which the e- are shared unequally.

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24

Polar molecule

: a molecule in which one side of the molecule is slightly negative & the opposite side is slightly positive

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25

Dipole

: a molecule that has two poles, or regions, with opposite charges

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26

Van der Waals forces

the two weakest intermolecular attractions-dispersion interactions & dipole forces.

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27
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29

Dipole interaction

intermolecular forces resulting from the attraction of oppositely charged regions of polar molecules

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30

Dispersion force

: attraction between molecules caused by the e- motion on one molecule affecting the e- motion on the other through electrical forces; weakest interactions between molecules.

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31
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32

Hydrogen bond

attractive forces in which a H covalently bonded to a very electronegative atom is also weakly bonded to an unshared e- pair of another electronegative atom.

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33

Network solid

a solid in which all of the atoms are covalently bonded to each other.

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