principles of chemistry

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describe the structure of solids

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1

describe the structure of solids

particles arranged regularily and packed closely together

vibrate in fixed positions

strong forces between particles

small amount of kinetic energy

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2

describe the structure of liquids

particles are mostly touching with some gaps

particles move about at random

medium forces between particles

moderate amount of kinetic energy

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3

descrive the structure of gases

particles move at random and quickly

particles are far apart

weak forces between particles

high amount of kinetic energy

collide with eachother and sides of container

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4

what is the proper name for the conversion of solid to liquid?

melting

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5

what is the proper name for the conversion between liquid and gas?

boiling / evaporating

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6

what is the proper name for the conversion between liquid and solid?

freezing

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7

Describe what happens when water vapour cools to form liquid water

particles lose kinetic energy

particles move closer together

particles move slower and less randomly

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8

describe what happens when liquid water boils to form water vapour

particles gain kinetic energy

particles move further apart

particles move quicker and more randomly

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9

describe what happens when liquid water cools to form ice

particles lose kinetic energy

particles move closer together

particles move slower and less randomly

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10

describe what happens when ice melts to form liquid water

particles gain kinetic energy and vibrate more

particles move further apart as forces of attraction are overcome

particles move quicker and more randomly

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11

how does evaporation occur?

particles in liquid have differing amounts of energy

particles with the greatest amount of kinetic energy break away from surface of liquid

average kinetic energy of remaining particles is lowered

in a closed container both evaporation and condensation occur simultaneously

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12

define diffusion

net movement of particles from an area of high concentration to an area of low concentration

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13

how can diffusion be demonstrated experimentally?

use cotton wool soaked in ammonia (NH3) and hydrochloric acid (HCl)

white ring forms closer to HCl end

tells you that NH3 diffuses faster

NH3 has a lower Mr, so is lighter

diffuses more quickly than HClOpen photo

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14

Define solvent

liquid in which a solute dissolves

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15

Define solute

a solid which dissolves in a solvent

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16

define solution

mixture of a solute and a solvent

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17

define a saturated solution

a solution where no more solute can dissolve in the solvent

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18

what is an element?

a substance which contains one type of atom only

cannot be split into anything simpler by any chemical means

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19

what is a compound?

a substance made up of two or more elements chemically combined

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20

what is a mixture?

a substance made up of two or more elements NOT chemically combined together

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21

what are some examples of elements?

iron, lead, sulfur, nitrogen, oxygen

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22

what are some examples of compounds?

calcium carbonate, ammonia, carbon dioxide, water, iron sulfide

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23

what are some examples of mixtures?

honey, air, sea water, blood, soup

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24

what is a pure substance?

contains one type of material only

eg. one type of element or molecule

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25

describe the melting and boiling points of pure substances

fixed

eg. boiling point of pure water is exactly 100 degrees celcius

eg. melting point of pure water is exactly 0 degrees celcius

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26

describe the melting and boiling points of mixtures

melts over a range of temperatures

boils over a range of temperatures

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27

what method is used to separate an insoluble solute from a solvent?

filtration

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28

what method is used to seperate a soluble solute from a solvent?

evaporation or distillation

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29

what method is used to seperate liquids of different boiling points?

fractional distillation

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30

what method is used to seperate pure water from sea water

simple distillation

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31

what method is used to seperate petrol and water and why is this used?

seperating funnel

petrol and water are immiscible (dont mix)

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32

what is paper chromatography used to seperate?

dyes/inks ie. liquids with different solubilities

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33

how do you carry out paper chromatography?

use a pencil line as reference line

add spots of ink/dye to pencil line

place filter paper in solvent

  • make sure solvent level is below pencil line

leave until solvent nearly reaches top of paper

allow to dry

furthest dot has the greatest solubility

<p>use a pencil line as reference line</p><p>add spots of ink/dye to pencil line</p><p>place filter paper in solvent</p><ul><li><p>make sure solvent level is below pencil line</p></li></ul><p>leave until solvent nearly reaches top of paper</p><p>allow to dry</p><p>furthest dot has the greatest solubility</p><p></p>
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34

why should the line be drawn in pencil?

pencil does not contain ink so does not run

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35

explain why it is important for the solvent level to be below the spots of dye

to prevent spots dissolving in the solvent

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36

how do you calculate the Rt value?

Rt = distance travelled by component / distance travelled by solvent

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