Review for Chem final

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Bond forming

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124 Terms

1

Bond forming

releases energy (exothermic)

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2

Bond breaking

endothermic (requires energy)

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3

Spontaneous

-ΔG, Decreasing the amount of available energy to perform work, happens naturally or without effort

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4

Nonspontaneous

ΔG, Increasing the amount of available energy to preform work, does not happen naturally or with effort

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5

Enthalpy

A measure of heat in a system

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6

Entropy

How much energy is spread out

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7

ΔH

Enthalpy

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8

ΔS

Entropy

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9

ΔG

Gibb's Free Energy

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10

How does adding a catalyst affect the rate of reaction?

It lowers the activation energy

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11

+ΔS

Increasing entropy/energy spreads out

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12

The change in entropy

ΔS

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13

heat of formation equation

sum of products - sum f products

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14

How does lowering the temperature affect a reactions rate?

The reaction gets slower

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15

How does decreasing the concentration of the reactants affect a reactions rate?

The reaction will increase

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16

Q=mc∆T

specific heat formula

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17

∆G=∆H-T∆S

Gibb’s free energy equation

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18

Activation energy

the minimum amount of energy required to start a chemical reaction

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19

Activated complex

The state of the particles that is in between the reactants and products

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20

Does the potential energy graph slope up or down in an endothermic reaction?

Up

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21

Does the potential energy graph slope up or down in an exothermic reaction?

Up a little bit an then down a lot

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22

Heat formation is defined as

The amount of heat absorbed

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23

Convection

A cyclic heat transfer in a liquid or solid

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24

Conduction

Heat is transferred between 2 objects that are in contact

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25

Radiation

Heat transfer without something touching

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26

1st law of thermodynamics

Energy cannot be created or destroyed

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27

What happens to the entropy of a solid to a liquid

Get bigger(more randomness)

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28

What happens to the entropy of a gas to a solid

Gets smaller(less randomness)

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29

What is equilibrium?

When the forward reactions equal the rate of the reverse reactions. The concentrations of its products and reactants will remain unchanged.

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30

What does K mean?

The equilibrium constant

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31

K>>1

The reaction if product-favored

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32

K<<1

The reaction is reactant-favored

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33

K=1

The reaction favors neither.

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34

LE CHATELIER’S PRINCIPLE

If an equilibrium is stressed, the equilibrium shifts in the direction that relieves the stress.

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35

What does not stress a system?

Catalysts and nobel gases

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36

What is a Reaction Quotient(Q)?

Describes the concentrations of a system to compare to the equilibrium constant (Kc) to determine if the system is at equilibrium.

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37

Q>K

then the reaction has more products than reactants, so we shift to the left! (Create more reactants)

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38

Q=K

then the reaction is at equilibrium!

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39

Q<K

then the reaction has more reactants than products, so we shift to the right! (Create more products)

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40
<p>what is this?</p>

what is this?

Reaction Quotient equation

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41

What happens when you increase the concentration of the reactants?

shift the equilibrium to the right (more product is created).

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42

What happens when you increase the concentration of the products?

shift the equilibrium to the left (more products dissociate into reactants)

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43

What happens when you decrease the concentration of the reactants?

shift the equilibrium to the left (less reactants to create products, so more products dissociate into reactants).

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44

What happens when you decrease the concentration of the products?

shift the equilibrium to the right (less products dissociate into reactants, so more reactants create products)

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45

What happens when you increase the pressure of a system?

the concentration of the molecules to increase on the side with more moles on it. Equilibrium shifts in the opposite direction.

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46

What happens when you decrease the pressure of a system?

Decreasing the pressure decreases the concentration of the side with more moles on it. equilibrium shifts in the opposite direction

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47

What happens when you increase the temperature in an exothermic reaction?

By increasing the heat, more AB products will be destroyed, shifting equilibrium to the left.

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48

What happens when you decrease the temperature in an exothermic reaction?

By decreasing the heat, more AB products will be created, shifting equilibrium to the right.

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49

What happens when you increase the temperature in an endothermic reaction?

By increasing the heat, more AB products will be destroyed, shifting equilibrium to the right.

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50

What happens when you decrease the temperature in an endothermic reaction?

By decreasing the heat, more AB products will be created, shifting equilibrium to the left.

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51

What is a solid?

Definitive shape and volume.

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52

What is a liquid?

Indefinite shape, but definite volume.

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53

What is a gas?

Indefinite shape and indefinite volume.

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54

What is plasma?

Gas with free flowing electrons

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55

Temperature is…

Temperature is the measure of the average kinetic energy of the molecules in a substance.

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56

What is melting?

Changing from solid to liquid

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57

What is vaporization?

Changing from liquid to gas

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58

What is condensation?

Changing from gas to liquid

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59

What is freezing?

Changing from liquid to solid

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60

What is sublimation?

Changing from solid to gas

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61

What is deposition?

Changing from gas to solid

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62

What are IMF’s?

are forces of attraction or repulsion between two molecules.

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63

Ion-diploe

strongest IMF, metal and non-metal, polar and non-polar

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64

Hydrogen Bonding

Hydrogen bonding is an attractive force that takes place between hydrogen atoms attached to ONLY Nitrogen, Oxygen, & Fluorine (NOF).

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65

Diploe-Diploe

Dipole-dipole IMFs take place between two polar molecules. Any molecules that are polar have dipole-dipole between them.

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66

LDF

All bonds are this, are weak partial attractions between two polar or nonpolar molecules

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67

What is evaporation?

is the process of liquid molecules becoming gaseous at any temperature.

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68

Does temperature change in a phase change?

NO!!!!

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69

What is Triple Point?

Pressure and temperature at which the substance exists as all the states of matter

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70

What is Critical Point?

Pressure and temperature when the compound becomes a supercritical fluid (fluid-gas hybrid)

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71

Molarity equation

Molarity=moles/liters of solution(l)

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72

What is diluting?

To dilute a liquid, means to make it less concentrated of a certain substance. This process is used to create a desired concentration from a substance.

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73

Dilutions equation

M1V1=M2V2

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74

What are COLLIGATIVE PROPERTIEs

Substances dissolve differently depending on the solute and solvent.

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75

Like Dissolves Like

Polar molecules dissolve polar molecules, nonpolar molecules dissolve nonpolar molecules.

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76

Soluble

Solid will dissolve

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77

Insoluble

Solid will not dissolve

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78

Miscible

Liquid will mix

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79

Immiscible

Liquid will not mix

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80

Unsaturated

More solute can be added to the mixture or the temperature can be decreased. No particles.(under the line)

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81

Saturated

The exact amount of temperature and particles, so that no more particles can be dissolved.

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82

Supersaturated

More solute exists in the solution than can be dissolved. Particles are present.

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83

Daltons Law

knowt flashcard image
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84

Boyle’s Law

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85

Charle’s Law

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86

Gay-lussac’s law

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87

Avogadro’s law

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88

Combined Gas Law

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89

Ideal gas law equation

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90

Moles at STP equal?

22.4L

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91

What is stoichiometry?

is the process of analyzing and calculating mass relationships in chemical reactions.

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92

What is a limiting reactant?

the reactant that gets used up first in a chemical reactant

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93

What is theoretical yield?

is the maximum amount of product that can be generated from a chemical reaction. Theoretically, all of the reactant will be used to create as much product as possible.

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94

What is actual yield?

is the amount of product that is ACTUALLY generated during a chemical reaction.

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95

What is percent yield?

The percent yield is the percentage of product that was actually created compared to what could theoretically be created.

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96

How do you find percent yield?

Actual/Theoretical ᐧ 100 = % Yield

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97

What is excess reactant?

the reactants that are not used up when the reaction is finished

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98

Amphoteric

  1. (of a compound, especially a metal oxide or hydroxide) able to react both as a base and as an acid.

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99

What is fission?

Fission occurs when a neutron hits a large, unstable nucleus and causes it to break into two smaller nuclei.

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100

What is critical mass?

is the amount of a substance that must be present in order for a chain reaction to occur.

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