Valence Bond Theory and Hybridization

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ฯƒ bond

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14 Terms

1

ฯƒ bond

cylindrically symmetric about the bond axis; no nodal plane along the bond axis

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2

๐œ‹ bond

electron density in 2 lobes with a single nodal plane along the bond axis

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3

Single bond

๐œ‹ bond

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4

Double bond

ฯƒ bond + ๐œ‹ bond

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5

Triple bond

ฯƒ bond + ๐œ‹ bond + ๐œ‹ bond

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6

Exception

single-bonded terminal atoms

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7

Electron promotion serves to

increase the number of unpaired electrons; if you have an empty orbital you can promote one of your electrons to that orbital

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8

The hybrid orbitals only differ in

their orientation in space

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9

2 hybrid orbitals =

sp

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10

3 hybrid orbitals =

spยฒ

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11

4 hybrid orbitals =

spยณ

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12

In valence bond theory, bonds result from

the pairing of unpaired electrons from the valence shell atomic orbitals

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13

Energy for the initial electron promotion comes from

bonding

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14

Molecules can't rotate around a

double bond

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