Thermodynamics

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Enthalpy change of formation

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22 Terms

1

Enthalpy change of formation

The enthalpy change when 1 mole of a compound is formed from its elements in their standard states under standard conditions

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2

Enthalpy change of dissociation

the nethalpy change when all the bonds of the same type in 1 mole of gaseous molecules are broken

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3

lattice enthalpy of formation

the enthalpy change when 1 mole of a solid ionic compound is formed from its gasous ions under standard conditions

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4

lattice enthalpy of dissociation

the enthalpy change when 1 mole of a solid ionic compound is completely dissolved into its gaseous ions under standard conditions

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5

enthalpy change of 1st ionisation

the enthalpy change when 1 mole of gaseous 1+ ions are formed from gaseous atoms

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6

enthalpy change of 2nd ionisation

The enthalpy change when 1 mole of gaseous 2+ ions are formed from 1 mole of gaseous 1+ ions

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7

enthalpy change of atomisation of an element

The enthalpy change when 1 mole of a gaseous atoms is formed from an element in its standard states

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8

enthalpy change of atomisation of a compound

The enthalpy change when 1 mole of a compound in its standard states is converted to gaseous atoms

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9

enthalpy change of 1st electron affinity

The enthalpy change when 1 mole of gaseous 1- ions are formed from 1 mole of gaseous atoms

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10

enthalpy change of 2nd electron affinity

The enthalpy change when 1 mole of gaseous 2- ions are formed from 1 mole of gaseous 1- ions

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11

enthalpy change of hydration

The enthalpy change when 1 mole of aqueous ions are formed from 1 mole of gaseous ions

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12

enthalpy change of solution

The enthalpy change when 1 mole of a solute is dissolved in enough solvent that when there is further dilution, there is no more enthalpy change

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13

entropy

the measure of disorder

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14

what does a thing having more entropy mean

it has more disorder

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15

what state has the least entropy

solid

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16

what states have the most entropy

liquid and gas

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17

entropy change calculation

ΔS = Sproducts - Sreactants

ΔS is in JK^-1mol-1

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18

what does the gibbs free energy calculation tell

if a reaction is feasible

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19

gibbs free energy calculation

ΔG (Jmol^-1) = ΔH (Jmol^-1) - TΔS (JK^-1mol^-1)

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20

what is ΔG when a reaction is feasible

0 or negative

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21

What may have an effect on feasibility

Temperature

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22

The temperature at which a reaction becomes just feasible can be calculated.

What is ΔG

What calculation is used

ΔG = 0

T = ΔH / ΔS

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