Chemical Equilibria

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Le Châteliers Principle

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1

Le Châteliers Principle

________: when a chemical system at equilibrium is disturbed, it returns to equilibrium by counteracting the disturbance.

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2

Solids

________ are always omitted from the expressions for Q and K.

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3

K

An increase in temperature will change K. It will increase ________ for an endothermic, and decrease ________ for an exothermic.

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4

chemical equilibrium

If a(n) ________ is disturbed by adding a reactant or product, the system will proceed in the direction that consumes part of the added species.

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5

Qc

________ can be calculated at any point in a reaction.

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6

Homogenous equilibrium

________: one in which all of the reactants and products are present in the same phase.

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7

Heterogenous equilibria

________: contain reactants and products that are in two or more different phases.

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8

concentration of products

The value of Qc depends on the ________ and reactants present at that particular moment.

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9

Equilibrium constant

________ (K): the value of Q when the reaction is at equilibrium.

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10

reversible reactions

For ________, catalysts increase the rates of the forward and ________.

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11

gas phase solutions

For ________, the equilibrium constant may be expressed in terms of either the molar concentrations (Kc) or partial pressures (Kp) of the reactants and products.

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12

SOLID

If what is added or removed is a(n) ________ or liquid, the reaction does not shift at all.

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13

K

If ________ is very small, the mixture contains mostly reactants at equilibrium.

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14

Equilibrium constant (K)

the value of Q when the reaction is at equilibrium

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15

When Q < K*

  • reaction must shift FORWARD

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16

When Q > K*

  • reaction must shift BACKWARD

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17

When Q = K*

  • reaction is at equilibrium, and will maintain constant concentration

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18

Homogenous equilibrium

one in which all of the reactants and products are present in the same phase

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19

Heterogenous equilibria

contain reactants and products that are in two or more different phases

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20

Le Châteliers Principle

when a chemical system at equilibrium is disturbed, it returns to equilibrium by counteracting the disturbance

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21

Result

A catalyst causes the system to reach equilibrium more quickly

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