Chemical Kinetics

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Kinetics

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19 Terms

1

Kinetics

Study of the rates of reactions and the steps by which the occur

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2

Endothermic

Pertaining to a chemical process that absorbs heat energy and produces positive change in enthalpy

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3

Exothermic

Pertaining to a chemical process that releases heat energy and produces a negative change in enthalpy

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4

Collision Theory Rule 1

Particles must collide before they can react. However, a collision alone doesn’t guarantee a reaction

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5

Collision Theory Rule 2

Be properly oriented for the necessary rearrangement of atoms and electrons

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6

Collision Theory Rule 3

Be forceful enough/possess enough energy to form products. Reactions follow only forceful, oriented collisions

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7

Activation energy

Minimum amount of kinetic energy that must be possessed by the colliding molecules before they react

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8

Activated complex

Colliding reactants that form a theoretical, transitional structure between reactant and product

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9

Reaction rates

tell how fast reactions change into products

<p>tell how fast reactions change into products</p>
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10

Factors that affect reaction rates

Nature of reactants, concentration, temperature, surface area, and presence of catalysts

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11

Nature of reactants

This controls the rate of the reaction. Reactive substances react quickly and vice versa. Some noble gases never react or barely do. Another variable is combination, H and Cl under certain conditions react vigorously.

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12

Concentration

This increases the rate of a reaction. Varies from reaction to reaction, it could double or even quadruple the rate

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13

Temperature

Reaction rates double for every 10 C in temperature. Higher temperatures increase number of collisions and the force of collisions

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14

Surface area

If a substance is broken up into smaller pieces more surface area is exposed causing it to react faster.

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15

Catalysts

A substance that changes a reaction rate without being permanently changed or consumed by the reaction. Has lower activation energy

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16

Enzymes

A class of catalysts that are naturally occurring biological substances

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17

Homogeneous catalyst

in the same phase as the reactants or in solution with a reactant

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18

Heterogeneous catalyst

a catalyst in a separate phase than the reactant

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19

Inhibitor

A substance used to reduce a catalysts undesirable effects.

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