Chemistry Prelim

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Steel

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89 Terms

1

Steel

Properties of Alloy: -Iron and carbon (elements) -Hard -High tensile strength

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Brass

Properties of Alloy: -Copper and zinc (elements) -Lustrous gold appearance -Hard but easily machined

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Solder

Properties of Alloy: -Tin and lead -Low melting point -Adheres firmly to other metals when molten

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4

Reduction

Process: To turn a metal oxide into pure metal involves the removal of the oxygen from the metal oxide

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5

Electrolysis

Chemical decomposition produced by passing an electric current through a liquid or solution containing ions.

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6

Alloy

Is a mixture of more than one metal to produce a material with specific physical and chemical properties

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7

Particle theory

All matter is made of continuously moving particles

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8

Law of conservation

Matter can be changed from one form into another, mixtures can be separate or made, and pure substances can be decomposed but the total mass remains constant.

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9

Delocalised Electron

An electron that has left its outer shell

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10

Isotopes

All atoms of the same element have the same number of protons in the nucleus, however they do not necessarily have the same mass. These atoms differ in the numver of neutrons and therefore mass number

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11

Lewis dot structure

A way of representing the valence electron configuration of an atom and show how valence electrons are arranged in compounds

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12

Ionisation energy

The amount of energy required to remove the most losely bound electron from an atom or ion in the gaseous state

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13

Covalent network

Properties of bond:

  • very high M.P and B.P

  • Non-conductors -Extremely hard

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14

Solute

A substance dissolved in another substance, usually the component of solution present in the lesser amount

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15

Solvent

A substance in which another substance is dissolved, forming a solution

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16

Solution

A homogeneous mixture of two or more substances, which may be solids, liquids, gases, or a combination of these

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Density

Mass/ volume

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18

Fossil fuels

Are formed when dead and decaying material burns before complete decomposition

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19

Coal

Often formed in swamps and mangroves

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20

Petroleum

Mostly formed from the remains of buried aquatic organisms (e.g. plankton) broken down by anaerobic bacteria

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21

Natural gas

Mostly the remains of buried aquatic organisms

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22

Catalyst

A substance that speeds up a chemical reaction, but is not consumed by the reaction hence a catalyst can be recovered chemically unchanged at the end of the reaction

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23

Hydrogen bonding

Occurs between hydrogen atoms and unshared pairs of electrons of N, O or F atoms- resulting in an unequal sharing of electrons leading to a partial positive charge on the H-atoms

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Alkanes

Single bond

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25

Alkenes

Double bond

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26

Alkynes

Triple bond

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27

Distillation

It works by evaporating tone of the liquid from the solution, it is then cooled and condensed into a separate container and the other liquid is left behind

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28

Viscosity

The resistance of a liquid to flow- it increases with stronger intermolecular forces and decreases with higher temperatures

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29

Saturated solution

A solution in which the maximum amount of a solvent has been dissolved. Once this is achieved an equilibrium is established

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30

Small molecule

Properties of a type of molecule:

  • Low B.P

  • Very volatile

  • Flows easily

  • Ignites easily

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31

Large molecule

Properties of a type of molecule:

  • High B.P

  • Not very volatile

  • Does not flow easily

  • Does not ignite easily

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32

Isomers

Compounds with the same molecular formula but different structural arrangements are known as structural isomers

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33

Induced intermolecular forces

When a charge on one object distorts the distribution of charge on a nearby object, producing an induction of charge and a force of attraction between the two objects e.g. rubbing a balloon on your skirt causes static in your hair

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34

Ion-induced intermolecular forces

The result of an ion distorting the electron density of a non-polar molecule

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35

Polarisability

The relative tendency of a charge distribution to be distorted from its normal shape by an external field

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36

Dispersion forces

The weakest kind of intermolecular attraction and occurs between molecules- they are caused by the motion of electrions

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37

Homologous series

Same pattern & similar formula- it is like the same molecule that is getting bigger

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38

Oxidation

loss of electrons to become a positive ion

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39

Bohr's model

Theory for the atom: o The nucleus is the central part of the atom that contains protons and neutrons o The electrons move through a relatively large space outside the nucleus in shells o The electrons are kept moving around the nucleus by electrostatic charges between the positively charged nucleus and negatively charged electrons

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40

Atomic radius

-Increase down a group as each successive element has one more electron shell- due to additional energy levels -Decrease left to right as more electronegative, the charge in the nucleus increase so the electrostatic force between the nucleus and the outer electrons is stronger holding it closer to the nucleus

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41

Electronegativity

-Increases across a period as atomic radius decreases -Decreases down a group as atomic radius increases

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42

Ionisation energy

-Increases from left to right as more electronegative -Decreases down a group as less electronegative (electrons further away from nucleus)

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43

Mendeleev

Developed a table of the elements based on increasing atomic weight

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44

Gay-Lussac

"When measured at constant temperature and pressure, the volumes of gases taking part in a chemical reaction show simple whole number ratios to one another."- theory

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45

Avogadro

"When measured at the same temperature and pressure, equal volumes of gases contain the same number of molecules." - Law

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46

Mineral

A natural substance occurring in the Earth's crust, which is a compound (hence pure) with a definite composition and crystalline structure e.g. Al2O3

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47

Ore

A compound or mixture of compounds (or minerals) from which it is economic to extract a substance such as a metal e.g. bauxite (contains mineral Al2O3)

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48

Polar molecule

A molecule in which there is an uneven charge distribution

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49

Dipole-dipole interaction

Occurs between oppositely charged ends of permanent polar

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50

Adhesive forces

(attraction between unlike molecules) pulls the molecules inward and closer together, making the liquid surface behave like an elastic skin under tension.

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51

Cohesive forces

(attractive forces between like molecules) cause the droplet to assume a spherical like shape to minimise the surface area.

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52

Surface tension

Is a measure of the energy needed to increase the surface area of a liquid by a unit amount.

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53

Precipitation

An insoluble ionic compound formed as a solid in solution from solutions of two soluble ionic compounds

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54

Precipitation reaction

Occurs when the force of attraction between the two ions is stronger than the electrostatic attraction between the water molecules and the ions

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55

Equilibrium

A dynamic situation in a closed system, where there is continual interchange between reactants and products in a reaction at the atomic level but with no observable change at the macroscopic level

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56

Concentration

The amount of a given substance dissolved in a specified amount of solution

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57

Specific heat capacity

The heat needed to raise the temperature of 1 unit mass of a substance by 1 Kelvin Degree

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58

Exothermic dissolution

A chemical dissolves in water and heat is released causing a temperature rise

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59

Dissolution

The action or process of dissolving

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60

Endothermic dissolution

A chemical dissolves in water and heat is absorbed causing a drop in temperature

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61

Thermal pollution

The discharge into a river or lake of quantities of hot water that are large enough to increase significantly the temperature of the water body

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62

Corrosion

Metal + Oxygen --> metal oxide

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63

Combustion

Fuel + oxygen ---> carbon dioxide + water

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64

Respiration

Glucose + oxygen ---> carbon dioxide + water

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65

Precipitation

Soluble salt + soluble salt ---> insoluble salt + soluble salt

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66

Neutralisation

Acid + Base ---> salt + water

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67

Gravimetric analysis

Is used to determine the mass and/ or percentage of different components in a sample (usually a mixture)

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68

Desalination

the process of removing dissolved salts and minerals from seawater or brackish water. It is also called desalting or by its shortened name, desa

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69

Copper

Can be used for electrical wires because they are generally ductile and good conductors of electricity

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70

Liquids

The particles have more space between them and have translational and vibrational motion (vibrate slightly and fill up what its contained in)

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Gases

The particles have a lot of energy, they don't interact with each other as much and have rapid translational motion

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72

Solids

The particles are orderly arranged and closely packed- because the particles are closely packed together in solids than in liquids, solids have greater densities (with the exception of water and ice)

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73

Mass number

protons + neutrons

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74

Atomic weight

Protons= electrons

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75

Ion

A charged particle formed when an atom gains or loses one or more electrons

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76

Covalent bonds

Are formed between two of more atoms sharing electrons

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77

Physical change

Do not involve the production of new substances, and are reversible

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78

Chemical change

form one or more new chemical substances

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79

Metallic bonding

Occurs between metals and involves the electrostatic attraction between delocalised electrons and the metal cations, which hold the 3D lattice together.

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80

Ionic bonding

Involves the transfer of electrons from one atom to another. The bonding consists of electrostatic attraction between the positive and negative ions formed by this transfer of electrons, which hold the 3D lattice together.

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81

Empirical formula

Is the simplest form of a compound and represents the simplest whole number ratio of atoms/ions in the crystal.

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82

Ionic bonds

Properties:

  • High melting and boiling points. Hard. Crystalline

  • Good electrical conductors when molten

  • Good electrical conductors when in solution

  • Poor electrical conductors when in solid.

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83

Covalent molecular

Properties:

  • Poor conductors of electricity in all states

  • Not hard

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84

Covalent network

Properties:

  • Poor conductors electricity in all states

  • Hardness

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85

Metallic bonds

Properties:

  • Good conductor of electricity

  • High melting and boiling points. Hard

  • Good conductor of heat

  • Malleable and ductile

  • Shiny lustre

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86

Immiscible

When they are mixed, they do not form a homogeneous liquid, but instead stay as drops of one liquid dispersed through the other liquid

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87

Allotropes

Are forms of the one element (in the same physical state) that have distinctly different physical properties

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88

Volatility

The ease with which it can be converted to a vapour; it decreases as boiling point increases

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89

Activation energy

Is the minimum amount of energy reactant molecules must possess in order to form products (kJ/mol), on an energy profile diagram, it is the space between the reactants and the peak

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