Endothermic
A reaction that requires the input of energy in order for the reaction to take place.
Exothermic
A chemical reaction that releases energy as one of its products.
Accelerants
Fuels that are easily vaporized and support combustion, and are highly exothermic.
ANFO
Ammonium nitrate; pellets of it are coated with fuel oil.
Wildfires
________ are either natural or deliberate.
Conflagration
The spark from the spark plug causes a very rapid combustion to take place.
Mass spectrometry
________ has added flexibility and refinement to GC analysis of fire scene evidence.
Arson
Fires that are deliberately set with criminal intent.
Solid Phase Microextraction
A fiber made from fused silica is coated with an adsorbent such as charcoal or Tenax.
Vapor Trace Analyzer
A detector that help aid sifting through evidence to find explosive residues from the scene.
Class IIIA
Flash point at or above 140°F (60°C) and below 200 °F (93.4°C)
Flash point
The lowest temperature that will allow a liquid to produce a flammable vapor.
Class IC
Flash point at or above 73 °F (22.8°C) and below 100°F (37.8 °C)
detonator
The ________ may be a blasting cap or other suitable primary explosive.
Mechanical fires
It happens when a machine overheats either through misuse or incorrect placement.
Target Compound Analysis
A profile of compounds that are present in each type of accelerant, such as gasoline, are monitored by the mass spectrometer.
Natural Fires
Caused by lightning strikes; flammable gases that escape from the ground around an oil field and combust.
Active Adsorption
Two tubes containing charcoal or Tenax are inserted partway into the container through holes in the top.
Black powder
________ is a finely milled mixture of carbon, sulfur, and potassium nitrate.
Blast Pressure
The wave that is created by this blast will shatter anything that gets in its way.
Explosive trains
________ may contain as few as two steps or up to four or more.
Low explosives
________ can be easily set off by using a flame, a spark, or chemicals such as acids.
V Patterns
If the point of origin is near a wall or corner of a room, smoke damage on the wall (s) usually occurs in a "V "shape.
Electrical Fires
________ happens due to malfunction of wirings or overheating.
Arson dogs
________ are specially trained dogs that can sniff out trace evidence of hydrocarbon accelerants.
Combustion
The reaction of a fuel with oxygen.
Smoke
Occurs when there is incomplete combustion in a fire.
Electron Capture Detector
Used to detect the presence of explosive residues.
Direct Ignition
It involves direct application of a spark or flame source to the fuel.
fire tetrahedron
The ________ depicts the four elements that must be present in order to have a fire: a source of heat or energy, fuel, source of oxygen, and chain reaction between the fuel and oxygen.
Deliberate Fires
Started with malicious intent involves a number of steps.
Low Order Explosion
One that takes place at less than optimal efficiency.
Material distortion
Metal and glass may melt or distort owing to high heat.
Smokeless powder
________ consists of small particles containing nitrocellulose (single base) or nitrocellulose and NG (double base)
Flame point
The highest temperature.
Selective Ion Monitoring
The mass spectrometer looks for particular ions that are characteristic of particular types of flammables.
Neat ignitable liquid
It may be possible to pour off the liquid from the residue, filter it to remove solid particulates, separate the hydrocarbon from the water, and make a direct injection into the gas chromatograph.
Class IA
Flash point below 73°F (22.8°C) and boiling point below 100 °F (37.8°C)
Class IB
Flash point below 73°F (22.8°C) and boiling point at or above 100 °F (37.8 °C)
Class II
Flash point at or above 100 °F (37 °C) and below 140 °F (60°C)
Class IIIB
Flash point at or above 200 °F (93.4 °C)
Low Burning
Fires generally start in a low area of a building
Wood charring
The depth of wood charring depends upon the intensity of the heat near the wood and the time of exposure
Spalling
_________ is the destruction of a surface due to heat or other factors
Weathering
used to describe the degradation of an accelerant due to heat or other environmental factors
Headspace Methods
a technique for sampling and examining the volatiles associated with a solid or liquid sample
Passive Adsorption
a small container of charcoal or Tenax or a plastic strip coated with one of them is placed or suspended inside the container
Active Adsorption
two tubes containing charcoal or Tenax are inserted partway into the container through holes in the top
Solid Phase Microextraction
a fiber made from fused silica is coated with an adsorbent such as charcoal or Tenax
Solvent Extraction
an evidence container is opened and a small quantity of a suitable solvent is added
Steam Distillation
Some of the accelerant residue is put in a distillation apparatus with some water, which is then boiled and distilled
Target Compound Analysis
a profile of compounds that are present in each type of accelerant, such as gasoline, are monitored by the mass spectrometer
Conflagration
the spark from the spark plug causes a very rapid combustion to take place
Negative Pressure Phase
not as powerful as the positive pressure blast phase but it is capable of doing additional serious damage to objects that have already been damaged by the initial blast
Low Explosives
have detonation velocities below 3280 fps
High Explosives
have detonation rates above 3280fps
Low Explosive Trains
One example would be a pipe bomb wherein a fuse made of black powder is used to detonate smokeless powder inside the pipe
High Explosive Trains
The final explosive is usually a secondary explosive
spontaneous combustion
Sometimes rags that have been used to clean up spills from kerosene or another fuel can heat up enough to cause “______” if they are left in a closed area for a long time.