First Law of Thermodynamics
the change in internal energy of a closed system is due to heat added or removed from the system and/or work done on or by the system
First Law of Thermodynamics formula
△U=Q-W
Isothermal
process or change taking place at a constant temperature
Isobaric
process in which pressure is constant
Heat Reservoir
a body whose mass is so large that, ideally, the temperature does does not change significantly when heat is exchanged
Second Law of Thermodynamics
heat energy flows spontaneously from a hot object to a cold object but not vice versa
it is impossible to construct a heat engine that is 100% efficient, a heat engine can convert some heat into useful work, but the rest must be exhausted in waste heat
the entropy of an isolated system never decreases, it can only stay the same or increase
Adiabatic
any process that occurs without heat gain or loss
efficiency of heat engine
e = 1 - Qc/Qh e = W/Qh
Carnot Engine
ideal engine, no energy loss due to internal friction, turbulence, etc.
Isochoric/Isovolumetric
process in which volume is constant
Refrigerators/Air Conditioners
operate by removing heat from low temperature reservoir and exhausting the heat to a higher temperature reservoir, work is done
efficiency of Refrigerators/Air Conditioners
Heat Engine
any device that changes thermal energy in to mechanical work
Heat Pump
a device that does work(W) to take heat from low temperatures(QL) and delivers it to warmer areas(QH)
Reversibillity
all processes are done so slowly that the whole process could be considered a series of equilibrium states so the whole process could be done in reverse with no magnitude, work done, or heat exchange/change
Entropy
the degree of disorder in a system, no thermal energy to convert to work
Heat Death
universe would be in maximum disorder, all matter would be uniform, everything would be one temperature, all energy would go to thermal energy, no work could be done
Greenhouse Effect
thermal radiation is absorbed by atmospheric greenhouse gases and is re-radiated everywhere
Thermal Pollution
heat output (QL) from every heat engine, this heat must then be absorbed by the environment
Solar Cell
converts sunlight directly into electricity without the use of a heat engine, photo voltaic cells
Thermodynamics
study of energy transformation in natural processes and involves relations among heat, work, and energy