Second Semester Chemistry Study Guide

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What information does a molecular formula provide?

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1

What information does a molecular formula provide?

the number and kind of atoms present in a molecule

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2

The molecule formula for the compound hydrogen cyanide is HCN. What information does the molecule formula provide about hydrogen cyanide?

one hydrogen atom, one carbon atom, and one nitrogen atom

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3

Why do atoms share electrons in covalent bonds?

to attain a noble-gas electron configuration

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4

Which noble gas has the same electron configuration as the oxygen in a water molecule?

neon

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5

What is the representative unit in a molecule compound?

a molecule

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6

Which of the following diatomic molecules is joined by a double covalent bond?

O2

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7

When H+ forms a bond with H2O to form the hydronium ion H3O+, this bond is called a coordinate covalent bond because

both bonding electrons come from the oxygen atom

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8

A resonance structure, like the one above, represents

a hybrid of the extremes represented by the resonance forms

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9

The side-by-side overlap of p orbitals produces what kind of bond?

pi bond

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10

Sigma bonds are formed as a result of the overlapping of which type(s) of atomic orbital(s)?

s and p

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11

According to VSEPR theory, molecule adjust their shapes to keep which of the following as far apart as possible?

pairs of valence electrons

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12

What causes water molecules to have a bent shape, according to VSPER theory?

repulsive forces between unshaped pairs of electrons

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13

Experimental evidence suggests that the H-C-H bond angles in ethene, C2H4, are

120 degrees

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14

Which of the forces of molecular attraction is the weakest?

dispersion

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15

What are the weakest attractions between molecules?

Van der Waals forces

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16

Why is hydrogen bonding only possible with hydrogen?

Hydrogen’s nucleus is electron deficient when it bonds with an electronegative atom

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17

What is required in order to melt a network solid?

breaking covalent bonds

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18

The wavelike properties of electrons are useful in

magnifying objects

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19

What are quanta of light called?

photons

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20

What is the number of electrons in the outermost energy level of an oxygen atom?

6

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21

What is the wavelength of an electromagnetic wave that travels at 3 × 108 m/s an has a frequency of 60 MHZ?

300,000,000m/s / 60,000,000 Hz

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22

Which electron configuration of the 4f energy sublevel is the most stable?

4f14

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23

Stable electron configurations are likely to contain

filled energy sublevels

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24

The atomic emission Spectra of a sodium atom on Earth and of a sodium atom in the sun would be

the same

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25

How many unpaired electrons are in a sulfur atom, which has the atomic number 16?

2

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26

What is the maximum number of orbitals in the p sublevel?

3

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27

What is the approximate energy of a photon having a frequency of 4 × 107 Hz?

3×10-26 J

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28

If three electrons are available to fill three empty 2p orbitals, how will the electrons be distributed in the three orbitals?

one electron in each orbital

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29

Which variable is directly proportional to frequency?

energy

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30

What is the approximate frequency of a photon having an energy 5 × 10-24 J?

8 X109 Hz

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31

What is the maximum number of d orbitals in a principal energy level?

5

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32

Which of the following electromagnetic waves have the highest frequencies?

gamma rays

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33

What is the maximum number of d orbitals in any single energy level in an atom?

7

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34

In an s orbital, the probability of finding an electron a particular distance from the nucleus can best be determined by the

quantum mechanical model

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35

Bohr’s model could only explain the spectra of which type of atoms?

single atoms with one electron

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36

How many half-filled orbitals are in a bromine atom?

1

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37

How can the position of a very tiny particle be determined?

by analyzing its interactions with another particle

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38

The quantum mechanical model of the atom

involves the probability of finding an electron in a certain position

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39

Which scientist developed the quantum mechanical model of the atom

Erwin Schrodinger

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40

Which of the following electron configuration of outer sublevels is the most stable?

4d5 5s1

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41

If the spin of one electron in an orbital is clockwise, what is the spin of the other electron in that orbital?

counterclockwise

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42

Who predicted that all matter can behave as waves as well as particles

Louis de Broglie

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43

In Bohr’s model of the atom, where are the electrons and protons located

The electrons move around the protons, which are at the center of the atom

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44

According to the Heisenberg uncertainty principle, if the position of a tiny moving particle is known, the

velocity of the particle cannot be exactly determined

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45

Emission of light from an atom occurs when an electron

drops from a higher to a lower energy level

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46

When an election moves from a lower to a higher energy level, the electron

absorbs a quantum of energy

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47

What is the shape of the 3p atomic orbital?

dumbbell

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48

By the early 1800’s, chemists organizing elements into groups because

there were so many new elements that had been discovered

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49

In which off the following groups of ions are the charges all shown corrrectly

Ca2+, Al3+, Br-

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50

Which of the following decreases with increasing atomic number in Group 2A

ionization energy

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51

Which of the following elements has the smallest atomic radius

chlorine

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52

Which of the following groupings contains only representative elements

Al, Mg, Li

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53

What is another name for the transition metals

Group B elements

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54

Which of the following factors contributes to the increase in ionization energy from left to right across a period?

An increase in the number of protons

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55

Which of the following statements is true about ions

When an anion forms, more electrons are transferred to it

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56

Which of the following elements has the smallest ionic radius

Li

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57

What is the element with the highest electronegativity value

fluorine

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58

Which of the following elements is a transition metal

copper

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59

Which of the following factors contributes to the decrease in ionization energy within a group in the periodic table as the atomic number increases

increases in atomic size

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60

Which of the following elements has the smallest first ionization energy

potassium

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61

What causes the shielding effect to remain constant across a period

electrons are added to the same principal energy level

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62

Which of the following elements has the lowest electronegativity

lithium

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63

Which of the following factors contributes to the increase in atomic size within a group in the periodic table as the atomic number increases

more shielding of the electrons in the highest occupied energy level

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64

Which of the following is true about the electron configurations of the representative elements

The highest occupied s and p sublevels are partially filled

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65

What is the charge of a cation

a positive charge

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66

How does atomic radius change from top to bottom in a group in the periodic table

It tends to increase

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67

Atomic size generally

decreases as you move from left to right across a period

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68

What is another name for the representative elements

Group A elements

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69

Which of the following is true abut the electron configurations of the noble gases

the highest occupied s and p sublevels are completely filled

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70

The atomic number of an element is the total number of which particles in the nucleus

protons

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71

Which of the following electron configurations is most likely to result in an element that is relatively inactive

a filled highest occupied principal energy level

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72

What is the element with the lowest electronegativity value

cesium

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73

Which of the following categories includes the majority of the elements

metals

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74

Which statement is true about electronegativity

Electronegativity generally increases from left to right across a period

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75

Of the elements Fe, Hg, U, and Te, which is a representative element

Te

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76

As you move from left to right across the second period of the periodic table

ionization energy increases

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77

in which of the following sets are the charges given correctly for all the ions

K+, Sr2+, O2-

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78

Of the following elements, which one has the smallest first ionization energy

aluminum

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79

Which subatomic particle plays the greatest part in determining the properties of an element

electron

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80

Which of the following statements correctly compares the relative size of an ion to its neutral atom

the radius of an anion is greater than the radius of its neutral atom

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81

What are the Group 1A and Group 7A elements examples of

represenative elements

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82

What is the energy required to remove an electron from the atom in the gaseous state called

ionization energy

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83

Which of the following statements is true about ions

Catons form when an atom loses electrons

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84

In which of the following sets is the symbol of the element, the number of protons, and the number of electrons given correctly

In, 49 portons, 49 electrons

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85

How many valence electrons are in an atom of phosphorus

5

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86

How many valence electrons does a helium atom have

2

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87

What is the name given to the electrons in the highest occupied energy level of an atom

valence electrons

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88

How many electrons does barium have to give up to achive a noble-gas electron configuration

2

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89

Which of the following ions has a pseudo-noble-gas configuration

Cu+

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90

Which of the following is a pseudo-noble-gas electron configuration

1s22s22p63s23p63d10

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91

What is the formula of the ion formed when phosphorus achieves a noble-gas configuration

p3-

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92

What is the elctron configuraation of the iodide ion

1s22s22p63s23p63d104s24p64d105s25p6

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93

How many valence electrons are transferred from the nitrogen atom to potassium in the formation of the compound potassium nitride

0

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94

What is the formula unit of sodium nitride

Na3N

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95

Alloys with a wide range of use are referred to as

steels

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96

Alloys are commonly used in manufacturing. Which if the following is a reason to use alloy instead of a pure metal

Bronze is tougher than pure copper

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97

Which of the following pairs of elements is most likely to form an ionic compound

magnesium and fluorine

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98

Which of the following is trueabout the melting temp of potassium chloride

The melting temp is relativily high

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99

Under what conditions can potassium bromide conduct electricity

only when melted or dissolved in water

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100

Wt characteristics of metals makes them good electrical conductors

they have mobile valence electrons

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