Atomic Trends in Periodic Tables

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Who created the Periodic Table

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Chemistry

The whole of Unit 5 - Atomic Number, Atomic Radii, Ionization energy, and Cations and Anions.

47 Terms

1

Who created the Periodic Table

Dmitri Mendeleev

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<p>How did Dmitri Mendeleev organize the periodic table</p>

How did Dmitri Mendeleev organize the periodic table

  • By increasing atomic mass

  • So that elements in the same row have similar properties

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Who refined the periodic table

Henry Moseley

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How did Henry Moseley rearrange the periodic table?

  • By increasing atomic number

  • What we use today

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Why is it better to organize the periodic table by increasing atomic number?

  • Atomic number (protons) determine the element

  • Helps to identify trends and patterns in properties (periodic law)

  • Reflects the arrangement of electrons in atoms.

  • Allows for easy comparison of elements in the same group.

  • Enables prediction of an element's properties based on its position.

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Periodic Law

When elements are arranged in order of increasing atomic number, there is a pattern in their physical and chemical properties

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Period

The horizontal rows of the periodic table

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Group

Vertical columns of the periodic table

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Elements in the same group…

Have similar properties

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Groups are numbered from..

1 to 18

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Elements in the same period…

  • Do not have similar properties.

  • But they have the same number of occupied energy levels

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<p>Representative Metals</p>

Representative Metals

S & P Blocks

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<p>Transition Metals</p>

Transition Metals

D Block

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<p>Inner Transition Metals</p>

Inner Transition Metals

F Block

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What are representative metals?

  • Alkali metals: Group 1 elements, highly reactive, soft metals

  • Alkaline earth metals: Group 2 elements, reactive but less than alkali metals

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Transition metals:

  • D-block elements, good conductors of heat and electricity

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Metalloids

Share properties between metals and nonmetals

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What are inner transition metals?

  • also known as lanthanides and actinides

  • are located at the bottom of the periodic table.

  • occupy f-orbitals in their electron configurations.

  • These elements possess unique properties and find applications in magnets, catalysts, and nuclear reactors.

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what are transition metals

  • filled in d orbitals.

  • They are found between alkaline earth metals and nonmetals.

  • These metals have high melting and boiling points, good conductivity, and can form colored compounds.

  • They are also known for multiple oxidation states and catalytic activity.

  • Examples include iron, copper, zinc, silver, and gold.

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Trends with atomic size

  • Atoms do not have fixed radius

  • The radius of an atom is found by measuring the nuclei in between two touching atoms of the same element and then halving that distance.

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Atomic Radius

½ of the radius between two nuclei of two like atoms

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Group trend of atomic size

Increases as you go down due to more occupied energy levels

  • More occupied energy levels = more orbits = greater atomic size

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Period trend of atomic size

Decreases from left to right

  • Shielding effect is constant between periods

  • Increased protons = increased nuclear charge = electrons are more attracted to center protons = less atomic size

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Shielding Effect

  • The more electrons which are closer to the proton results in outer electrons being repelled due to increase in negative charge.

  • As negatives and negatives repel —> Outer electrons are repelled and move into farther away energy orbitals.

  • Thus outer electrons have less attraction to nucleus

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<p>Atomic Size</p>

Atomic Size

  • Increases from top to bottom

  • Decreases from left to right

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How did Dmitri Mendeleev organize the periodic table

Energy required to remove an electron from a gaseous atom

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Ionization depends on…

  • Distance between electrons and nucleus

  • Nuclear charge (# of protons)

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How did Henry Moseley rearrange the periodic table?

  • By increasing atomic number

  • What we use today

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Period Trend for Ionization Energy

Increases as you go to the right as there is an increased nuclear charge (higher proton number)

  • More protons = electrons are more attracted to proton

  • More attraction between electrons and protons = harder to remove electron thus higher ionization energy

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Does it require more energy when removing a 2nd or 3rd electron?

  • Yes, the ionization energy is much higher

  • As the 2nd or 3rd electron removed from an atom tend to be closer to the proton

  • Meaning that they will have a higher pull which is harder to break than with the outer and farthest electron

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Isoelectronic with a noble gas means that..

There will be a very large increase of ionization energy when an electron is very

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Properties of Nonmetals

Generally tend to be the opposite of metals

  • Brittle (breaks easily)

  • Dull

  • Poor conductors of heat or electricity

  • Good insulator

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Why is it that atoms isoelectronic to noble gases have high ionization energy levels?

  • Isoelectronic with a noble gas means having the same number of electrons as a noble gas.

  • Noble gases have full electron shells, making them stable.

  • Removing an electron from an isoelectronic species disrupts this stability, requiring a significant amount of energy

  • Ionization energy increases substantially.

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Cations Ionic Size

  • Smaller than neutral atom from which they were made from

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Why are cations smaller than their neutral atoms?

  • Loss of energy levels (loss of orbitals = less rings around atom)

  • More protons than electrons means that more electrons will be pulled closer to nucleus

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Cation Ionic Size trends

The more electrons lost, the smaller the ion becomes

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Anions Ionic Size

Anions are always larger than their neutral atoms

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Why do anions increase in size than their neutral atoms?

  • More electrons than protons result in less attractive force to proton

  • Electrons that are less attracted to protons will be farther away

  • Increase in electrons = more electron orbitals

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Properties of metals

  • Lustrous (shiny)

  • Good conductors of heat and electricity

  • Malleable (Example: Aluminium can be split into thin sheets)

  • Ductile (Can be turned into metals)

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Anion Ionic Size Trends

The more electrons gained, the bigger the ion becomes

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Electronegativity

Ability for an element to attract other electrons when a compound (when it is chemically combined with another element)

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Highest electronegativity level

4.0

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Group trends for electronegativity level

Decreases as you go down

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Why does electronegativity decrease as you go down?

  • More electrons = more electrons farther away from nucleus

  • Less electrons attracted to nucleus = less electronegativity

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Period trend for electronegativity

  • Increases from left to right

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Why does electronegativity increase across a period?

  • More nuclear charge (more protons) = electrons will be more attracted to nucleus

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