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identify how to measure the mass of gas given off in a reaction
Measuring the speed of a reaction that produces a gas can be carried out using a mass balance
As the gas is released, the mass disappearing is measured on the balance
The quicker the reading on the balance drops, the faster the reaction
If you take measurements at regular intervals, you can plot a rate of reaction graph and find the rate quite easily (see page 107 for more)
This is the most accurate of the three methods described because the mass balance is very accurate. But it has the disadvantage of releasing the gas straight into the room
identify how to measure the volume of gas given off in a reaction
This involves the use of a gas syringe to measure the volume of gas given off
The more gas given off during a given time interval, the faster the reaction
Gas syringes usually give volumes accurate to the nearest cm3, so they're quite accurate. You can take measurements at regular intervals and plot a rate of reaction graph using this method too. You have to be quite careful though
identify which factors affect the rate of reactions
explain how changes of surface area affect rates
If one of the reactants is a solid, then breaking it up into smaller pieces will increase its surface area to volume ratio
This means that for the same volume of the solid, the particles around it will have more area to work on
rate of reaction=
amount of reactant used or amount of product formed/ time
collision theory
states that atoms, ions, and molecules must collide in order to react
identify catalysts in reactions
Enzymes are biological catalysts
explain catalytic action
A catalyst is a substance that speeds up a reaction, without being used up in the reaction itself. This means it's not part of the overall reaction equation
Different catalysts are needed for different reactions, but they all work by decreasing the activation energy needed for the reaction to occur. They do this by providing an alternative reaction pathway with a lower activation energy
activation energy
the minimum amount of energy required to start a chemical reaction
Identify a reversible reaction
Equilibrium
a state in which opposing forces are balanced
describe how equilibrium is reached
As the reactants react, their concentrations fall
identify reactants and products in a reversible reaction
If the equilibrium lies to the right, the concentration of products is greater than that of the reactants. If the equilibrium lies to the left, the concentration of reactants is greater than that of the products.
The position of equilibrium depends on what conditions?
the temperature
the pressure (this only affects equilibria involving gases)
the concentration of the reactants and products
Le Chatelier's Principle
States that if a stress is applied to a system at equilibrium, the system shifts in the direction that relieves the stress.
PRACTICAL: precipitation and colour change
You can record the visual change in a reaction if the initial solution is transparent and the product is a precipitate which clouds the solution (it becomes opaque).
You can observe a mark through the solution and measure how long it takes for it to disappear
PRACTICAL: change in mass (usually gas given off)
Measuring the speed of a reaction that produces a gas can be carried out using a mass balance.
As the gas is released, the mass disappearing is measured on the balance.
The quicker the reading on the balance drops, the faster the reaction.
If you take measurements at regular intervals, you can plot a rate of reaction graph and find the reaction quite easily.
This is the most accurate of the three methods described because the mass balance is very accurate. But it has the disadvantage of releasing the gas straight into the room.
PRACTICAL: The volume of gas given off
This involves the use of a gas syringe to measure the volume of gas given off.
The more gas given off during a given time interval, the faster the reaction.
Gas syringes usually give volumes accurate to the nearest cm3, so they're quite accurate. You can take measurements at regular intervals and plot a rate of reaction graph using this method too.
PRACTICAL: magnesium and HCl react to produce H2 gas
Start by adding a set volume of dilute hydrochloric acid to a conical flask.
Now add some magnesium ribbon to the acid and quickly attach an empty gas syringe to the flask.
Start the stopwatch. Take readings of the volume of gas in the gas syringe at regular intervals.
Plot the results in a table.
Now you can plot a graph with time on the x
PRACTICAL: sodium thiosulphate and HCl produce a cloudy precipitate
These two chemicals are both clear solutions. They react together to form a yellow precipitate or sulphur.
Start by adding a set volume of dilute sodium thiosulphate to a conical flask.
Place the flask on a piece of paper with a black cross drawn on it.
Add some dilute HCl to the flask and start the stopwatch.
Now watch the black cross disappear through the cloudy sulphur and time how long it takes to go.
alkane
saturated hydrocarbon with the general formula CnH2n+2, for example, methane, ethane, and propane
alkene
unsaturated hydrocarbon which contains a carbon
Complete combustion
When a substance burns with a good supply of oxygen the products are carbon dioxide and water.
cracking
the reaction used in the oil industry to break down large hydrocarbons into smaller, more useful ones
Crude oil
A mixture of hydrocarbons found underground in rocks formed over millions of years from the remains of sea creatures.
distillation
separation of a liquid from a mixture by evaporation followed by condensation
double bond
a covalent bond made by the sharing of two pairs of electrons
Finite resource
A resource that cannot be replaced once it has been used.
flammable
easily ignited and capable of burning rapidly
fraction
hydrocarbons with similar boiling points separated from crude oil
fractional distillation
a way to separate liquids from a mixture of liquids by boiling off the substances at different temperatures, then condensing and collecting the liquids
general formula
a formula that represents the common structure of all compounds in a single class of chemicals. For example, the general formula of all alkanes is CnH2n+2
hydrocarbon
a compound containing only hydrogen and carbon
Incomplete combustion
When a substance burns with a poor supply of oxygen the products are carbon monoxide and water.
mixture
when some elements or compounds are mixed together and intermingle but do not react together (i.e. no new substance is made). A mixture is not a pure substance
oxidised
a substance that has had oxygen added to it/ or has lost electrons
saturated hydrocarbon
describes a hydrocarbon with only single bonds between its carbon atoms. This means that it contains as many hydrogen atoms as possible in each molecule
thermal decomposition
the breakdown of a compound by heating it
unsaturated hydrocarbon
a hydrocarbon whose molecules contains at least one carbon
viscosity
the resistance of a liquid to flowing or pouring; a liquid's 'thickness'
functional group
an atom or group of atoms that give organic compounds their characteristic reactions
homologous series
a group of related organic compounds that have the same functional group