CHAPTER 22: CHEMISTRY OF THE NONMETALS 

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86 Terms

1

Asbestos

________- is a general term applied to a group of fibrous silicate minerals.

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2

Covalent carbides

________ are formed by boron and silicon.

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3

Sodium

________ hypochlorite- the active ingredient in many liquid bleaches.

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4

symbol D

It is not radioactive, and it is often given the ________ in chemical formulas.

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5

Carbon

________ is a nonmetal; silicon and germanium are metalloids; tin and lead are metals.

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6

Diamond

________- a clear, hard solid in which the carbon atoms form an sp^3 hybridized covalent network.

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7

Tritium

________- a radioactive isotope of hydrogen with a mass approximately three times that of the common protium isotope.

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8

room temperature

At ________, dioxygen is a colorless and odorless gas.

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9

Ionic Hydrides

________- are formed by the alkali metals and by the heavier alkaline earths (Ca, Sr, and Ba)

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10

Chlorine

________ is also used in water treatment to oxidize and thereby destroy bacteria.

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11

Oxygen

________ is used together with acetylene in oxyacetylene welding.

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12

Deuterium

________- makes up 0.0156 % of naturally occurring hydrogen.

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13

Calcite

________- is the principal mineral in limestone and the main constituent of marble, chalk, pearls, coral reefs, and the shells of marine animals such as clams and oysters.

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14

SiO2

It occurs in ________ and in an enormous variety of silicate minerals.

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15

Goiter

________- lack of iodine in the diet results in an enlarged thyroid gland.

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16

organic compounds

About half of the chlorine is used to manufacture chlorine- containing ________, such as the vinyl chloride used in making PVC plastics.

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17

H2

When ________ is ignited in air, a vigorous reaction occurs, forming H2O.

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18

reduction of dilute

It can be prepared in the laboratory by ________ nitric acid, using copper or iron as a reducing agent.

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19

Boron

________ is the only group 3A element that can be considered nonmetallic.

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20

Molecular Hydrides

________- are formed by nonmetals and metalloids, are either gases or liquids under standard conditions.

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21

Graphite

________- a soft, black, slippery solid that has a metallic luster and conducts electricity; it consists of parallel sheets of sp^2 hybridized carbon atoms held together by dispersion forces.

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22

Disproportionation

________- an element is simultaneously oxidized and reduced.

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23

Hydrogen

________ is also used to manufacture methanol via the catalytic reaction of CO and H2 at high pressure and temperature.

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24

polishes

They are used commercially in a wide variety of products, including lubricants, car ________, sealants, and gaskets.

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25

Nitrogen

________ dioxide- a yellow- brown gas.

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26

Nitrous oxide

________- also known as laughing gas because a person becomes giddy after inhaling a small amount.

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27

Teflon

________- a polymeric fluorocarbon noted for its high thermal stability and lack of chemical reactivity.

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28

Charcoals

________- formed when wood is heated strongly in the absence of air.

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29

Zone

________ Refining- can help further purify the element.

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30

important component

It is a(n) ________ of the upper atmosphere, where it screens out ultraviolet radiation and so protects us from the effects of these high- energy rays.

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31

Peroxides

________- compounds containing O- O bonds and oxygen in the- 1 oxidation state.

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32

Liquid heliumis

________ used as a coolant to conduct experiments at very low temperatures.

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33

Ammonia

________- a colorless, toxic gas that has a characteristic irritating odor; one of the most important compounds of nitrogen.

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34

Photocopy machines

________ contain a belt or drum coated with a film of selenium.

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35

Dioxygen

________ is only slightly soluble in water (0.04 g /L, or 0.001 M at 25 °C), but its presence in water is essential to marine life.

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36

key element

It is a(n) ________ in living organisms, compounds of nitrogen are not abundant in Earths crust.

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37

Ozone

________ is sometimes used to treat drinking water.

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38

Space Shuttle

Combustion of hydrogen- oxygen mixtures is used in liquid- fuel rocket engines such as those of the ________.

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39

Argon

________ is also used as a protective atmosphere to prevent oxidation in welding and certain high- temperature metallurgical processes.

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40

pulp

It is also used to bleach ________ and paper.

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41

Iodine

________ is commonly used as KI in table salt.

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42

Hydrogen peroxide

________ is marketed as a chemical reagent in aqueous solutions of up to about 30 % by mass.

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43

Elemental sulfur

________ is yellow, tasteless, and nearly odorless.

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44

Crystalline silicon

________ is a gray metalliclooking solid that melts at 1410 °C.

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45

Metallic Hydrides

________- are formed when hydrogen reacts with transition metals.

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46

fabric

When applied to a(n) ________, the oxygen atoms form hydrogen bonds with the molecules on the surface of the ________.

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47

Interstitial carbides

________ are formed by many transition metals.

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48

Selenium

________ is used in photoelectric cells and light meters because its electrical conductivity increases greatly upon exposure to light.

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49

Nitric

________ oxide- also a colorless gas but, unlike N2O, it is slightly toxic.

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50

Hydrogen

means "water producer,"; named by Antoine Lavoisier

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51

Protium

the most common isotope of hydrogen, has a nucleus consisting of a single proton, which makes up 99.9844% of naturally occurring hydrogen

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52

Deuterium

makes up 0.0156% of naturally occurring hydrogen

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53

Deuteration

a process of replacing protium with deuterium, which can also have a profound effect on reaction rates, a phenomenon called a kinetic-isotope effect

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54

Tritium

a radioactive isotope of hydrogen with a mass approximately three times that of the common protium isotope

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55

Ionic Hydrides

are formed by the alkali metals and by the heavier alkaline earths (Ca, Sr, and Ba)

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56

Metallic Hydrides

are formed when hydrogen reacts with transition metals

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57

Molecular Hydrides

are formed by nonmetals and metalloids, are either gases or liquids under standard conditions

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58

Fluorine is used to prepare fluorocarbons

very stable carbon-fluorine compounds used as refrigerants, lubricants, and plastics

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59

Teflon

a polymeric fluorocarbon noted for its high thermal stability and lack of chemical reactivity

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60

Sodium hypochlorite

the active ingredient in many liquid bleaches

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61

Goiter

lack of iodine in the diet results in an enlarged thyroid gland

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62

Acidic anhydrides/oxides

oxides that form acids when they react with water

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63

Basic anhydrides/oxides

ionic oxides that dissolve in water form hydroxides

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64

Peroxides

compounds containing O-O bonds and oxygen in the -1 oxidation state

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65

Super Oxide

a compound that contains the superoxide ion, which has the chemical formula O−

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66

Disproportionation

an element is simultaneously oxidized and reduced

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67

Hydrazine

another important hydride of nitrogen

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68

Nitrous oxide

also known as laughing gas because a person becomes giddy after inhaling a small amount

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69

Nitric oxide

also a colorless gas but, unlike N2O, it is slightly toxic

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70

Nitrogen dioxide

a yellow-brown gas

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71

The importance of the element stems in large part from its occurrence in all living organisms

Life as we know it is based on carbon compounds

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72

Graphite

a soft, black, slippery solid that has a metallic luster and conducts electricity; it consists of parallel sheets of sp^2 hybridized carbon atoms held together by dispersion forces

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73

Carbon Black

used as a pigment in black inks; large amounts are also used in making automobile tires

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74

Charcoals

formed when wood is heated strongly in the absence of air

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75

Diamond

a clear, hard solid in which the carbon atoms form an sp^3 hybridized covalent network

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76

Carbon monoxide

is formed when carbon or hydrocarbons are burned in a limited supply of oxygen

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77

Carbon dioxide

is produced when carbon-containing substances are burned in excess oxygen

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78

Carbonic acid

is a weak diprotic acid

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79

Principal Carbonate Minerals

Calcite, Magnesite, Dolomite & Siderite

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80

Calcite

is the principal mineral in limestone and the main constituent of marble, chalk, pearls, coral reefs, and the shells of marine animals such as clams and oysters

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81

Zone Refining

can help further purify the element

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82

Silicate

Silicon atom is surrounded by four oxygens and silicon is found in its most common oxidation state, +4

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83

Asbestos

is a general term applied to a group of fibrous silicate minerals

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84

Borane anions

boron and hydrogen form a series of anions

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85

Boric Oxide

the only important oxide of boron

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86

Boron Hydrides

boron forms a variety of compounds with hydrogen

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