Chapter13:Acid and Bases 

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Kw

ion- product constant (or the dissociation constant for water)

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Oxyacids

________- acidic proton is attached to an oxygen atom.

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Vinegar

contains acetic acid and is used in salad dressings.

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Arrhenius concept

acids produce hydrogen ions in aqueous solution, while bases produce hydroxide ions.

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Conjugate base

everything that remains of the acid molecule after a proton is lost.

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Salts

that consist of the cations of strong bases and the anions of strong acids have no effect on [H+] when dissolved in water.

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Acid base equilibria

must focus on the solution components and their chemistry.

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Common ion effect

shift in equilibrium position that occurs because of the addition of an ion already.

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Amphoteric

can behave either as an acid or as a base.

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amount of protons

Buffering capacity- ________ or hydroxide ions the buffer can absorb without a significant change in pH.

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Acid strength

equilibrium position of its dissociation (ionization) reaction.

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Lewis base

an electron- pair donor.

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conjugate acid

Kb always refers to the reaction of a base with water to form the ________ and the hydroxide ion.

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Organic acids

acids with a carbon atom backbone, commonly contain the carboxyl group.

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Conjugate acid

formed when the proton is transferred to the base.

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Arrhenius concept

acids produce hydrogen ions in aqueous solution, while bases produce hydroxide ions

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Brønsted-Lowry model

an acid is a proton (H+) donor, and a base is a proton acceptor

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conjugate base

everything that remains of the acid molecule after a proton is lost

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conjugate acid

formed when the proton is transferred to the base

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conjugate acid-base pair

two substances related to each other by the donating and accepting of a single proton

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Ka

acid dissociation constant

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Acid strength

equilibrium position of its dissociation(ionization) reaction

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strong acid

equilibrium lies far to the right

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weak acid

equilibrium lies far to the right

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diprotic acid

acid having two acidic protons

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oxyacids

acidic proton is attached to an oxygen atom

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Organic acids

acids with a carbon atom backbone, commonly contain the carboxyl group

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monoprotic acids

acid having one acidic protons

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amphoteric

can behave either as an acid or as a base

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Kw

ion-product constant (or the dissociation constant for water)

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pH scale

represent solution acidity

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acid-base equilibria

must focus on the solution components and their chemistry

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triprotic acid

acid having three acidic protons

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Lewis Acid-base model

An even more general model for acid-base behavior

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Lewis acid

an electron-pair acceptor

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Lewis base

an electron-pair donor

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common ion effect

shift in equilibrium position that occurs because of the addition of an ion already

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38
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buffered solution

resists a change in its pH when either hydroxide ions or protons are added

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buffering capacity

amount of protons or hydroxide ions the buffer can absorb without a significant change in pH

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