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4.2: solutions and dilutions

solution basics

  • solution: a homogenous mixture of two or more pure substances

    • the solvent is present in the greatest amount possible

    • all other substances are solutes

  • suspension: a heterogeneous mixture in which solute-like particles settle out of a solvent-like phase after mixing

  • colloid: a solution that has particles which remain evenly distributed throughout the solution; the particles do not settle to the bottom of the container, and they do not filter

term

meaning

example (bolded)

solute

what is being dissolved

sugar in water

solvent

what does the dissolving

sugar in water

soluble

can be dissolved

sugar can dissolve in water

insoluble

cannot be dissolved

sand cannot dissolve in water

how solutions form

  • “like dissolves like”—the more similar the solvent and solute molecules are, the more likely one substance is to be soluble in another

  • polar water molecules are able to dissolve an ionic compound like NaCl

  • polar water molecules are not able to dissolve a non-polar compound like propane

electrolytes

  • electrolyte: a substance that forms ions (charged particles or species) when dissolved in water

    • ionic compounds are electrolytes

  • strong electrolytes dissociate completely when dissolved in water (lots of ions)

  • weak electrolytes only partially dissociate when dissolved in water (fewer ions)

  • non-electrolyte: a substance that does not form ions when dissolved in water

    • covalent compounds are non-electrolytes

      • eg. sugar—dissolves in water but doesn’t form ions

types of solutions

  • solutions are categorized into one of three groups: saturated solutions, unsaturated solutions, and supersaturated solutions

    • these are based on the amount of solute dissolved within them

  • unsaturated solution: a solution that has less than the maximum amount of solute dissolved in the solvent (for that temperature)

    • you can continue to add solute and it will continue to dissolve

  • saturated solution: a solution in which the solvent holds as much solute as is possible at that temperature

    • saturation is dependent on temperature

  • supersaturated solution: a solution in which the solvent holds more solute than is typically possible at a given temperature

factors that affect how fast a substance dissolves

factor

definition

agitation

stirring helps solute particles dissolve faster because it increases the rate at which the solute particles come in contact with solvent particles

particle size

generally, the smaller the solute particle size, the faster it will dissolve. smaller particle size = more surface area = increased rate of contact with the solvent

temperature

some solutes dissolve faster at higher temperatures. higher temperature = more kinetic energy = higher rate of contact with solvent

concentration

a measurement of the amount of solute dissolved in the volume of solvent. there are many different ways to measure concentration, eg. molarity, percent by mass, percent by volume

finding percent by mass and percent by volume of a solution

  • percent by mass: ([solute mass/solution mass] x 100)

  • percent by volume: ([solute volume/solution volume] x 100)

dilutions

  • dilution: the process of adding more solvent to a solution without adding more solute, which decreases the concentration of a solution

    • eg. only adding water to the solution; that means that the number of moles of solute stays the same, only the volume of the solution changes

  • used to weaken the properties of the solute

  • “dilution” can also be used to describe the liquid itself that has been diluted

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4.2: solutions and dilutions

solution basics

  • solution: a homogenous mixture of two or more pure substances

    • the solvent is present in the greatest amount possible

    • all other substances are solutes

  • suspension: a heterogeneous mixture in which solute-like particles settle out of a solvent-like phase after mixing

  • colloid: a solution that has particles which remain evenly distributed throughout the solution; the particles do not settle to the bottom of the container, and they do not filter

term

meaning

example (bolded)

solute

what is being dissolved

sugar in water

solvent

what does the dissolving

sugar in water

soluble

can be dissolved

sugar can dissolve in water

insoluble

cannot be dissolved

sand cannot dissolve in water

how solutions form

  • “like dissolves like”—the more similar the solvent and solute molecules are, the more likely one substance is to be soluble in another

  • polar water molecules are able to dissolve an ionic compound like NaCl

  • polar water molecules are not able to dissolve a non-polar compound like propane

electrolytes

  • electrolyte: a substance that forms ions (charged particles or species) when dissolved in water

    • ionic compounds are electrolytes

  • strong electrolytes dissociate completely when dissolved in water (lots of ions)

  • weak electrolytes only partially dissociate when dissolved in water (fewer ions)

  • non-electrolyte: a substance that does not form ions when dissolved in water

    • covalent compounds are non-electrolytes

      • eg. sugar—dissolves in water but doesn’t form ions

types of solutions

  • solutions are categorized into one of three groups: saturated solutions, unsaturated solutions, and supersaturated solutions

    • these are based on the amount of solute dissolved within them

  • unsaturated solution: a solution that has less than the maximum amount of solute dissolved in the solvent (for that temperature)

    • you can continue to add solute and it will continue to dissolve

  • saturated solution: a solution in which the solvent holds as much solute as is possible at that temperature

    • saturation is dependent on temperature

  • supersaturated solution: a solution in which the solvent holds more solute than is typically possible at a given temperature

factors that affect how fast a substance dissolves

factor

definition

agitation

stirring helps solute particles dissolve faster because it increases the rate at which the solute particles come in contact with solvent particles

particle size

generally, the smaller the solute particle size, the faster it will dissolve. smaller particle size = more surface area = increased rate of contact with the solvent

temperature

some solutes dissolve faster at higher temperatures. higher temperature = more kinetic energy = higher rate of contact with solvent

concentration

a measurement of the amount of solute dissolved in the volume of solvent. there are many different ways to measure concentration, eg. molarity, percent by mass, percent by volume

finding percent by mass and percent by volume of a solution

  • percent by mass: ([solute mass/solution mass] x 100)

  • percent by volume: ([solute volume/solution volume] x 100)

dilutions

  • dilution: the process of adding more solvent to a solution without adding more solute, which decreases the concentration of a solution

    • eg. only adding water to the solution; that means that the number of moles of solute stays the same, only the volume of the solution changes

  • used to weaken the properties of the solute

  • “dilution” can also be used to describe the liquid itself that has been diluted