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2.2: isotopes, isotope structures, and calculating average atomic mass

the structure of atoms—subatomic particles

protons

  • positively charged (+)

  • located inside the nucleus

  • relatively massive

neutrons

  • no charge—neutral (/)

  • located inside the nucleus

  • relatively massive

electrons

  • negatively charged (-)

  • located outside nucleus in orbitals

  • extremely small compared to protons and neutrons

  • do not appreciably contribute to the mass of the atom (which is generally calculated with protons and neutrons)

charge is determined by the combination of protons and electrons; neutrons have no effect as they have no charge.

isotopes

  • isotopes: atoms of the same element with different masses

  • have different numbers of neutrons, but the same number of protons

  • atom: has a neutral charge (# of protons = # of electrons)

  • ion: has a charge (positive or negative; # of protons =/= # of electrons)

  • atomic number: the number of protons in the nucleus of an element

  • the atomic number “defines” an element and contributes to its placement on the periodic table

  • eg. aluminum has atomic number 13, which means that every aluminum atom has 13 protons in its nucleus

  • z is shorthand for atomic number

  • for Al, z=13

  • mass number: the number of protons + the number of neutrons in the nucleus of an atom

  • A is shorthand for mass number

  • in a neutral atom, the number of protons = the number of electrons

  • isotope symbols

atomic mass

  • atoms have extremely small masses

  • the heaviest naturally occurring atoms (uranium atoms) have a mass of roughly 4 x 10^-22 g

  • a mass scale on the atomic level is used to determine average atomic mass, where an atomic mass unit (AMU) is the base unit

  • 1 AMU = 1.66054 x 10^-24 g

atomic mass (weight) measurement

  • atomic and molecular weight can be measured with great accuracy using a mass spectrometer

  • masses of atoms are compared to the carbon atom with 6 protons and 6 neutrons

  • in the real world, we use large amounts of atoms and molecules, so we use average masses in calculations

  • an average mass is found using all isotopes of an element weighted by their relative abundances

average atomic mass

  • average atomic mass: the weighted average of the masses of all the isotopes of the element

R

2.2: isotopes, isotope structures, and calculating average atomic mass

the structure of atoms—subatomic particles

protons

  • positively charged (+)

  • located inside the nucleus

  • relatively massive

neutrons

  • no charge—neutral (/)

  • located inside the nucleus

  • relatively massive

electrons

  • negatively charged (-)

  • located outside nucleus in orbitals

  • extremely small compared to protons and neutrons

  • do not appreciably contribute to the mass of the atom (which is generally calculated with protons and neutrons)

charge is determined by the combination of protons and electrons; neutrons have no effect as they have no charge.

isotopes

  • isotopes: atoms of the same element with different masses

  • have different numbers of neutrons, but the same number of protons

  • atom: has a neutral charge (# of protons = # of electrons)

  • ion: has a charge (positive or negative; # of protons =/= # of electrons)

  • atomic number: the number of protons in the nucleus of an element

  • the atomic number “defines” an element and contributes to its placement on the periodic table

  • eg. aluminum has atomic number 13, which means that every aluminum atom has 13 protons in its nucleus

  • z is shorthand for atomic number

  • for Al, z=13

  • mass number: the number of protons + the number of neutrons in the nucleus of an atom

  • A is shorthand for mass number

  • in a neutral atom, the number of protons = the number of electrons

  • isotope symbols

atomic mass

  • atoms have extremely small masses

  • the heaviest naturally occurring atoms (uranium atoms) have a mass of roughly 4 x 10^-22 g

  • a mass scale on the atomic level is used to determine average atomic mass, where an atomic mass unit (AMU) is the base unit

  • 1 AMU = 1.66054 x 10^-24 g

atomic mass (weight) measurement

  • atomic and molecular weight can be measured with great accuracy using a mass spectrometer

  • masses of atoms are compared to the carbon atom with 6 protons and 6 neutrons

  • in the real world, we use large amounts of atoms and molecules, so we use average masses in calculations

  • an average mass is found using all isotopes of an element weighted by their relative abundances

average atomic mass

  • average atomic mass: the weighted average of the masses of all the isotopes of the element