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Chapter 24 - Organic Chemistry

24.1 - Classes of Organic Compounds

  • Organic chemistry is the branch of chemistry that deals with carbon compounds.

  • Organic compounds can be classified based on the functional groups they contain.

    • A functional group is a collection of atoms that are substantially responsible for the parent molecule's chemical behavior.

  • Because they are only made up of hydrogen and carbon, most organic substances are derived from a category of compounds called hydrocarbons.

  • Aromatic hydrocarbons contain one or more benzene rings, whereas aliphatic hydrocarbons do not contain the benzene group or the benzene ring.

24.2 - Aliphatic Hydrocarbons

  • The general formula for alkanes is CnH2n + 2, where n = 1, 2

    • Alkane hydrocarbon molecules are distinguished by the presence of only single covalent bonds.

    • Because they contain the greatest amount of hydrogen atoms that may link with the number of carbon atoms present, alkanes are known as saturated hydrocarbons.

    • Cycloalkanes are alkanes that have their carbon atoms arranged in a ring.

Hydrocarbons

  • Unsaturated hydrocarbons, or alkenes, are molecules containing double or triple carbon-carbon bonds that allow them to incorporate hydrogen atoms.

    • Additional reactions, in which one molecule adds to another to generate a single product, are common in unsaturated hydrocarbons.

24.3 - Aromatic Hydrocarbons

  • The substitution reaction, in which an atom or group of atoms replaces an atom or group of atoms in another molecule, is the most typical reaction of halogens with benzene.

  • In substances, benzene rings can be fused together to produce an enormously large number of compounds.

  • Naphthalene, which is used in mothballs is the best known of these compounds.

    • The coal tar contains these and many similar compounds.

  • Some of the compounds with several rings can cause cancer in humans and other animals.

    • They are potent carcinogenic.

24.4 - Chemistry of the Functional Groups

  • The hydroxyl functional group, —OH, is found in all alcohols.

  • The R—O—R′ connection is found in ethers, where R and R′ are hydrocarbon groups.

    • They are created when an alkoxide reacts with an alkyl halide.

  • Condensation reaction involves the combining of two molecules and the removal of a small molecule, usually water.

  • At least one hydrogen atom is connected to the carbon in the carbonyl group in an aldehyde.

    • The carbonyl group's carbon atom is linked to two hydrocarbon groups in a ketone.

  • The general formula for esters is R′COOR, where R′ might be H or a hydrocarbon group and R is also a hydrocarbon group.

    • Esters are utilized in the confectionery and soft-drink industries as flavoring ingredients and the production of perfumes.

  • Saponification traditionally referred to the alkaline hydrolysis of fatty acid esters to produce soap molecules.

    • Saponification has evolved into a catch-all term for the alkaline hydrolysis of any ester.

  • Amines are organic bases with the formula R3N, where R might be hydrogen or a hydrocarbon group.

BS

Chapter 24 - Organic Chemistry

24.1 - Classes of Organic Compounds

  • Organic chemistry is the branch of chemistry that deals with carbon compounds.

  • Organic compounds can be classified based on the functional groups they contain.

    • A functional group is a collection of atoms that are substantially responsible for the parent molecule's chemical behavior.

  • Because they are only made up of hydrogen and carbon, most organic substances are derived from a category of compounds called hydrocarbons.

  • Aromatic hydrocarbons contain one or more benzene rings, whereas aliphatic hydrocarbons do not contain the benzene group or the benzene ring.

24.2 - Aliphatic Hydrocarbons

  • The general formula for alkanes is CnH2n + 2, where n = 1, 2

    • Alkane hydrocarbon molecules are distinguished by the presence of only single covalent bonds.

    • Because they contain the greatest amount of hydrogen atoms that may link with the number of carbon atoms present, alkanes are known as saturated hydrocarbons.

    • Cycloalkanes are alkanes that have their carbon atoms arranged in a ring.

Hydrocarbons

  • Unsaturated hydrocarbons, or alkenes, are molecules containing double or triple carbon-carbon bonds that allow them to incorporate hydrogen atoms.

    • Additional reactions, in which one molecule adds to another to generate a single product, are common in unsaturated hydrocarbons.

24.3 - Aromatic Hydrocarbons

  • The substitution reaction, in which an atom or group of atoms replaces an atom or group of atoms in another molecule, is the most typical reaction of halogens with benzene.

  • In substances, benzene rings can be fused together to produce an enormously large number of compounds.

  • Naphthalene, which is used in mothballs is the best known of these compounds.

    • The coal tar contains these and many similar compounds.

  • Some of the compounds with several rings can cause cancer in humans and other animals.

    • They are potent carcinogenic.

24.4 - Chemistry of the Functional Groups

  • The hydroxyl functional group, —OH, is found in all alcohols.

  • The R—O—R′ connection is found in ethers, where R and R′ are hydrocarbon groups.

    • They are created when an alkoxide reacts with an alkyl halide.

  • Condensation reaction involves the combining of two molecules and the removal of a small molecule, usually water.

  • At least one hydrogen atom is connected to the carbon in the carbonyl group in an aldehyde.

    • The carbonyl group's carbon atom is linked to two hydrocarbon groups in a ketone.

  • The general formula for esters is R′COOR, where R′ might be H or a hydrocarbon group and R is also a hydrocarbon group.

    • Esters are utilized in the confectionery and soft-drink industries as flavoring ingredients and the production of perfumes.

  • Saponification traditionally referred to the alkaline hydrolysis of fatty acid esters to produce soap molecules.

    • Saponification has evolved into a catch-all term for the alkaline hydrolysis of any ester.

  • Amines are organic bases with the formula R3N, where R might be hydrogen or a hydrocarbon group.