Nuclear Chemistry
Elements undergo chemical changes so it can become more stable.
Stability depends on the proton to neutron ratio.
Atomic numbers < 20 are the most stable because the ratio is about 1:1
Henri Becquerel called emission from decay uranic rays because they were emitted from uranium.
Marie Curie discovered Po (Polonium) and Ra (Radon) which emitted uranic rays, changing uranic rays to radioactivity.
Radioactivity: emission of subatomic particles or high energy electromagnetic radiation by nuclei. such atoms/isotopes said to be radioactive
Nuclear Decay:
protonsnucleons, (neutrons + protons)X
An unstable nucleus undergoes a change and reduction in energy to become more stable.
The four types of nuclear decay (+ gamma)
Alpha decay
largest ionizing power, lowest penetrating power
can penetrate matter
nucleus emits alpha particle
# nucleons must =, # protons must =
24He is the alpha particle. It is always one of the daughter particles.
Beta decay
high speed electron is ejected from a nucleus
turns neutron into proton
it has a lower ionizing power than alpha particle but a higher penetration power
Positron emission
positron is antiparticle of e
collision with e causes gamma ray emission
cause: too little neutrons
proton converted into neutron, emits positron
Gamma decay
electromagnetic radiation
high-energy photons
no charge, no mass
usually emitted in conjunction with other radiation types
lowest ionizing power, highest penetrating power
requires several inches lead shielding
Electron capture
particle absorbed by unstable nucleus
converts proton into neutron
different from beta decay! 2 reactants, 1 product
Nuclear decay series:
Uranium has an atomic number greater than 83. Therefore it is naturally radioactive.
Uranium decays into Thorium by alpha decay.
Thorium decays into Protactinium by alpha decay.
Protactinium decay next and so on until we reach a stable non-reactive element.
Nuclear half-life:
Unstable nuclei emit either an alpha, beta, or positron particle to try to shed mass or improve their neutron to proton ratio.
You cannot predict when an oculus will disintegrate for individual nuclei, but you can when you look at large # of atoms.
The half-life of any nuclide does not depend on temperature, pressure, or amount of material left. It depends on the N/P ratio.
Loss of mass to decay
**
**
Amount of Beanium | 64 | 32 | 16 | 8 | 4 | |
---|---|---|---|---|---|---|
Fraction left | 1 | 1/2 | 1/4 | 1/8 | 1/16 | 1/2^x |
# Half life | 1 | 2 | 3 | 4 | x |
Nuclear Chemistry
Elements undergo chemical changes so it can become more stable.
Stability depends on the proton to neutron ratio.
Atomic numbers < 20 are the most stable because the ratio is about 1:1
Henri Becquerel called emission from decay uranic rays because they were emitted from uranium.
Marie Curie discovered Po (Polonium) and Ra (Radon) which emitted uranic rays, changing uranic rays to radioactivity.
Radioactivity: emission of subatomic particles or high energy electromagnetic radiation by nuclei. such atoms/isotopes said to be radioactive
Nuclear Decay:
protonsnucleons, (neutrons + protons)X
An unstable nucleus undergoes a change and reduction in energy to become more stable.
The four types of nuclear decay (+ gamma)
Alpha decay
largest ionizing power, lowest penetrating power
can penetrate matter
nucleus emits alpha particle
# nucleons must =, # protons must =
24He is the alpha particle. It is always one of the daughter particles.
Beta decay
high speed electron is ejected from a nucleus
turns neutron into proton
it has a lower ionizing power than alpha particle but a higher penetration power
Positron emission
positron is antiparticle of e
collision with e causes gamma ray emission
cause: too little neutrons
proton converted into neutron, emits positron
Gamma decay
electromagnetic radiation
high-energy photons
no charge, no mass
usually emitted in conjunction with other radiation types
lowest ionizing power, highest penetrating power
requires several inches lead shielding
Electron capture
particle absorbed by unstable nucleus
converts proton into neutron
different from beta decay! 2 reactants, 1 product
Nuclear decay series:
Uranium has an atomic number greater than 83. Therefore it is naturally radioactive.
Uranium decays into Thorium by alpha decay.
Thorium decays into Protactinium by alpha decay.
Protactinium decay next and so on until we reach a stable non-reactive element.
Nuclear half-life:
Unstable nuclei emit either an alpha, beta, or positron particle to try to shed mass or improve their neutron to proton ratio.
You cannot predict when an oculus will disintegrate for individual nuclei, but you can when you look at large # of atoms.
The half-life of any nuclide does not depend on temperature, pressure, or amount of material left. It depends on the N/P ratio.
Loss of mass to decay
**
**
Amount of Beanium | 64 | 32 | 16 | 8 | 4 | |
---|---|---|---|---|---|---|
Fraction left | 1 | 1/2 | 1/4 | 1/8 | 1/16 | 1/2^x |
# Half life | 1 | 2 | 3 | 4 | x |