knowt logo

Nuclear Chemistry

  • Elements undergo chemical changes so it can become more stable.

  • Stability depends on the proton to neutron ratio.

    • Atomic numbers < 20 are the most stable because the ratio is about 1:1

  • Henri Becquerel called emission from decay uranic rays because they were emitted from uranium.

  • Marie Curie discovered Po (Polonium) and Ra (Radon) which emitted uranic rays, changing uranic rays to radioactivity.


Radioactivity: emission of subatomic particles or high energy electromagnetic radiation by nuclei. such atoms/isotopes said to be radioactive


Nuclear Decay:

  • protonsnucleons, (neutrons + protons)X

  • An unstable nucleus undergoes a change and reduction in energy to become more stable.

  • The four types of nuclear decay (+ gamma)

    • Alpha decay

      • largest ionizing power, lowest penetrating power

      • can penetrate matter

      • nucleus emits alpha particle

      • # nucleons must =, # protons must =

      • 24He is the alpha particle. It is always one of the daughter particles.

    • Beta decay

      • high speed electron is ejected from a nucleus

      • turns neutron into proton

      • it has a lower ionizing power than alpha particle but a higher penetration power

    • Positron emission

      • positron is antiparticle of e

      • collision with e causes gamma ray emission

      • cause: too little neutrons

      • proton converted into neutron, emits positron

    • Gamma decay

      • electromagnetic radiation

      • high-energy photons

      • no charge, no mass

      • usually emitted in conjunction with other radiation types

      • lowest ionizing power, highest penetrating power

      • requires several inches lead shielding

    • Electron capture

      • particle absorbed by unstable nucleus

      • converts proton into neutron

      • different from beta decay! 2 reactants, 1 product

  • Nuclear decay series:

    • Uranium has an atomic number greater than 83. Therefore it is naturally radioactive.

    • Uranium decays into Thorium by alpha decay.

    • Thorium decays into Protactinium by alpha decay.

    • Protactinium decay next and so on until we reach a stable non-reactive element.




Nuclear half-life:

  • Unstable nuclei emit either an alpha, beta, or positron particle to try to shed mass or improve their neutron to proton ratio.

  • You cannot predict when an oculus will disintegrate for individual nuclei, but you can when you look at large # of atoms.

  • The half-life of any nuclide does not depend on temperature, pressure, or amount of material left. It depends on the N/P ratio.

  • Loss of mass to decay

    • **
      **

Amount of Beanium

64

32

16

8

4


Fraction left

1

1/2

1/4

1/8

1/16

1/2^x

# Half life


1

2

3

4

x

P

Nuclear Chemistry

  • Elements undergo chemical changes so it can become more stable.

  • Stability depends on the proton to neutron ratio.

    • Atomic numbers < 20 are the most stable because the ratio is about 1:1

  • Henri Becquerel called emission from decay uranic rays because they were emitted from uranium.

  • Marie Curie discovered Po (Polonium) and Ra (Radon) which emitted uranic rays, changing uranic rays to radioactivity.


Radioactivity: emission of subatomic particles or high energy electromagnetic radiation by nuclei. such atoms/isotopes said to be radioactive


Nuclear Decay:

  • protonsnucleons, (neutrons + protons)X

  • An unstable nucleus undergoes a change and reduction in energy to become more stable.

  • The four types of nuclear decay (+ gamma)

    • Alpha decay

      • largest ionizing power, lowest penetrating power

      • can penetrate matter

      • nucleus emits alpha particle

      • # nucleons must =, # protons must =

      • 24He is the alpha particle. It is always one of the daughter particles.

    • Beta decay

      • high speed electron is ejected from a nucleus

      • turns neutron into proton

      • it has a lower ionizing power than alpha particle but a higher penetration power

    • Positron emission

      • positron is antiparticle of e

      • collision with e causes gamma ray emission

      • cause: too little neutrons

      • proton converted into neutron, emits positron

    • Gamma decay

      • electromagnetic radiation

      • high-energy photons

      • no charge, no mass

      • usually emitted in conjunction with other radiation types

      • lowest ionizing power, highest penetrating power

      • requires several inches lead shielding

    • Electron capture

      • particle absorbed by unstable nucleus

      • converts proton into neutron

      • different from beta decay! 2 reactants, 1 product

  • Nuclear decay series:

    • Uranium has an atomic number greater than 83. Therefore it is naturally radioactive.

    • Uranium decays into Thorium by alpha decay.

    • Thorium decays into Protactinium by alpha decay.

    • Protactinium decay next and so on until we reach a stable non-reactive element.




Nuclear half-life:

  • Unstable nuclei emit either an alpha, beta, or positron particle to try to shed mass or improve their neutron to proton ratio.

  • You cannot predict when an oculus will disintegrate for individual nuclei, but you can when you look at large # of atoms.

  • The half-life of any nuclide does not depend on temperature, pressure, or amount of material left. It depends on the N/P ratio.

  • Loss of mass to decay

    • **
      **

Amount of Beanium

64

32

16

8

4


Fraction left

1

1/2

1/4

1/8

1/16

1/2^x

# Half life


1

2

3

4

x