Chemistry IGCSE

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  • refinery gas

  • gasoline

  • naphtha

  • kerosene

  • diesel oil

  • fuel oil

  • lubricating fraction

  • bitumen

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98 Terms

1
  • refinery gas

  • gasoline

  • naphtha

  • kerosene

  • diesel oil

  • fuel oil

  • lubricating fraction

  • bitumen

Order of fractions in refining petroleum (top to bottom):

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bottled gas for heating and cooking

Refinery gas use:

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petrol for cars

Gasoline uses:

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making chemicals and plastics

Naphtha uses:

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fuel for aeroplanes, oil stoves and oil lamps

Kerosene uses:

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fuel for diesel engines

Diesel oil uses:

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power stations, ships, home heating systems

Fuel oil uses:

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lubricants for car engines, machinery, waxes and polishes

Lubricating fraction uses:

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making roads, covering roofs

Bitumen uses:

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breaks non-useful long chain alkanes to smaller alkanes and at least one alkene

Cracking alkanes:

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  • vaporised alkanes are passed over a catalyst

  • requires 600-700°C

  • requires silica or alumina/zeolite catalysts

Cracking alkanes process:

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bromine water goes from orange to colourless thanks to an addition reaction

Identification of alkenes:

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  • alkene + hydrogen —> alkane

  • requires a nickel catalyst

  • requires 150°C

Hydrogenation reactions:

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  • alkene + steam —> alcohol

  • requires 300°C

  • requires 60-70 atm of pressure

  • requires a phosphoric acid catalyst

Hydration reaction:

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  • alkane + oxygen —> carbon dioxide + water (+ heat)

Combustion of alkanes:

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  • alkane + chlorine gas —> hydrogen chloride + chloroalkanes

  • requires UV light (photochemical reaction)

Substitution reaction between alkanes and chlorine:

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  • heat

  • pressure

  • catalyst

Polymerisation of alkenes requires:

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white

Anhydrous copper (II) sulfate colour:

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blue

Hydrated copper (II) sulfate colour:

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blue

Anhydrous cobalt (II) chloride colour:

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pink

Hydrated cobalt (II) chloride colour:

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air

Source of nitrogen for the Haber process:

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process to make ammonia

Haber process:

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methane

Source of hydrogen for Haber process:

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450°C, 200 atm, iron catalyst

Typical conditions of the Haber process:

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process to produce sulfuric acid

Contact process:

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burning sulfur, roasting sulfide ores

Source of sulfur dioxide in Contact process:

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air

Source of oxygen for Contact process:

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450°C, 2 atm, vanadium oxide catalyst

Typical conditions for the conversion of sulfur dioxide to trioxide in the Contact process:

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purple to colourless when mixed with a reducing agent

Acidified KMnO4 colour changes

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colourless to reddish-brown when mixed with an oxidising agent

Aqueous Potassium iodide colour changes

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platinum and rhodium

Catalytic converter catalyst

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6.02×10²³

Avogadro constant (number of particles per mol)

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anode: bromine (brown gas)

cathode: lead (dark grey metal coat)

Electrolysis of molten lead(II) bromide

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anode: chlorine (green bubbles)

cathode: hydrogen bubbles

Electrolysis of concentrated aq. sodium chloride (brine)

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anode: oxygen bubbles

cathode: hydrogen bubbles

Electrolysis of dilute sulfuric acid:

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anode: oxygen bubbles

cathode: copper (red-brown metal coating)

Electrolysis of aq copper (II) sulfate with non-copper electrodes:

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anode: oxygen bubbles + electrode shrinks

cathode: electrode gets bigger

Electrolysis of aq copper (II) sulfate with copper electrode:

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all soluble

Solubility of sodium salts

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all soluble

Solubility of potassium salts:

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all soluble

Solubility of ammonium salts:

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all soluble

Solubility of nitrate salts:

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all soluble except lead and silver

Solubility of chloride salts:

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all soluble except barium, calcium and lead

Solubility of sulfate salts:

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all insoluble except potassium, ammonium and sodium

Solubility of carbonate salts:

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all insoluble except sodium, ammonium, potassium, and calcium (partially)

Solubility of hydroxide salts

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CO3 2- test

Add dilute acid, CO2 bubbles

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Cl- test

Acidify with nitric acid, add silver nitrate. White precipitate formed (AgCl)

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I- test

Acidify with nitric acid, add silver nitrate. Yellow precipitate formed (AgI)

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Br- test

Acidify with nitric acid, add silver nitrate. Cream precipitate formed (AgBr)

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NO3- test

Add NaOH, add aluminium gently. Ammonia formed.

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SO4 2- test

Acidify, add barium nitrate. White precipitate (Barium Sulfate) forms

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SO3 2- test

Add dilute HCl, warm gently. SO2 produced.

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Al 3+ and aq NaOH

White precipitate. Clear solution. Soluble in excess.

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Al 3+ and aq NH3

White precipitate. Insoluble in excess.

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NH4 + and aq NaOH

Red brown precipitate, insoluble in excess

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Ca 2+ and aq. NaOH

White precipitate. Insoluble in excess

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Ca 2+ and aq. NH3

Nothing

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Cr 3+ and aq NaOH

Greenish precipitate, insoluble in excess.

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Cr 3+ and aq NH3

Greenish precipitate, insoluble in excess

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Cu 2+ and aq NaOH

Blue precipitate, insoluble in excess

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Cu 2+ and aq. NH3

Turquoise precipitate, dark blue solution in excess.

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Fe 2+ and aq. NaOH

Green precipitate in clear solution, insoluble in excess.

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Fe 2+ and aq. NH3

Greenish precipitate, insoluble in excess.

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Fe 3+ and aq. NaOH

Orange-brown precipitate, insoluble in excess

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Fe 3+ and aq. NH3

Orange-brown precipitate, insoluble in excess.

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Zn 2+ and aq. NaOH.

White precipitate, clear colourless solution, soluble in excess,

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Zn 2+ and aq. NH3

White precipitate, colourless solution in excess

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Ammonia test

Turns damp red litmus paper on top of container blue

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CO2 test

Limewater turns milky

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H2 test

Lit splint, squeaky pop

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O2 test

Glowing splint relights

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SO2 test

Turns acidified KMnO4 from purple to colourless

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Cl2 test

Bleaches damp litmus paper

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Li+ flame test

red

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Na+ flame test

yellow

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K+ flame test

lilac

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Ca 2+ flame test

red

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Ba 2+ flame test

green

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Cu 2+ flame test

blue-green

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Graphite structure

  • Allotrope of carbon

  • Each carbon atoms forms covalent bonds with 3 others, forming hexagons of strong bonds

  • The atoms each lose the fourth electron, which stays between layers and holds the layers together with weak electrostatic forces

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Diamond structure

  • Allotrope of carbon

  • Each carbon atom forms 4 covalent bonds with 4 other atoms

  • Forms a tetrahedron

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Silicon (IV) dioxide structure

  • Each silicon atom forms covalent bonds with 4 oxygen atoms, and each oxygen atom forms covalent bonds with 2 silicon atom

  • forms tetrahedron structure

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Flue gas desulfurisation

reacting sulfur dioxide in flue gas with calcium oxide to remove sulfur

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Relative mass of an electron

1/2000

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Top number in an atomic symbol

Mass number

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Bottom number in an atomic symbol

Proton number

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Properties of ionic compounds:

  • high melting and boiling point (strong intermolecular forces between oppositely charged ions)

  • conduct electricity when molten/aqueous

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Properties of covalent bonds:

  • strong intramolecular forces

  • weak intermolecular forces

  • low boiling and melting point

  • electrical insulator

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How do enzymes work?

provide a pathway that needs less activation energy

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Formula of hydrated copper sulfate:

CuSO4.5H2O

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Formula of hydrated cobalt chloride:

CoCl2.6H2O

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Flame colour vs alkane chain length:

Short chain: blue flame, little smoke

Long chain: yellow smoky flame

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