Kinetics and Equilibrium Test

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Kinetics

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1

Kinetics

Branch of chemistry that is concerned with the rates of chemical reactions

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2

Steps of a Chemical Reaction

  1. 2 reactants are allowed to collide - the minimum energy colliding particles must have to react is called the activation energy

  2. During a reaction, particles that are neither reactants nor products momentarily form an activation complex

    • Activation complex - the arrangement of atoms at the peak of the activation energy barriers

  3. Formation of products

    • Exothermic - energy is released

    • Endothermic - energy is absorbed

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3

Le Chatelier’s Principle

If a system at equilibrium is subjected to stress, the equilibrium is shifted to the direction that tends to relieve the stress

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4

Le Chatelier’s Principle: Effect on Pressure

  • Affects systems in which only gases are involved

  • For pressure to affect a gaseous system, the total number of moles on the left side must be different from the total number of moles on the right

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5

Common Ion Effect

The addition of an ion common to 2 solutes brings about precipitation or reduced ionization

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6

Equilibrium Equation

  • Keq = [P]/[R]

  • do not include (s) or (l)

  • coefficient —> exponent

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