Kinetics
Branch of chemistry that is concerned with the rates of chemical reactions
Steps of a Chemical Reaction
2 reactants are allowed to collide - the minimum energy colliding particles must have to react is called the activation energy
During a reaction, particles that are neither reactants nor products momentarily form an activation complex
Activation complex - the arrangement of atoms at the peak of the activation energy barriers
Formation of products
Exothermic - energy is released
Endothermic - energy is absorbed
Le Chatelier’s Principle
If a system at equilibrium is subjected to stress, the equilibrium is shifted to the direction that tends to relieve the stress
Le Chatelier’s Principle: Effect on Pressure
Affects systems in which only gases are involved
For pressure to affect a gaseous system, the total number of moles on the left side must be different from the total number of moles on the right
Common Ion Effect
The addition of an ion common to 2 solutes brings about precipitation or reduced ionization
Equilibrium Equation
Keq = [P]/[R]
do not include (s) or (l)
coefficient —> exponent